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Synthesis and structure of cadmium complexes [Me3BuN] 2 + [CdI4]2−, [Ph3(PhCH2)P] 2 + [Cd2I6]2−, [Me3EtN] n + [CdI3] n − , and [Me3NH] n + [CdI3] n −

“…For example, two cadmium atoms are linked by two bridging iodine atoms in the centrosymmetric anion of the complex [1].…”

“…The reaction of tetraphenylstibonium with cad mium iodide is known to produce complex [1]. To continue the works on synthesis of cadmium complexes, here we studied reactions of cadmium iodide with ammonium and phosphonium iodides.…”

Triarylantimony dicarboxylates as pseudo-halides for palladium-catalyzed cross-coupling reaction with arylboronic acids and triarylbismuthanes without any base

“…Thin-layer chromatography (TLC) was performed with Macherey-Nagel Pre-coated TLC plates Sil G25 UV 254 . The group 15 metal reagents, triphenylantimony dibromide (3) [21], triarylantimony diacetates such as 6a [5], 6b [5], 6c [2c], 6d [12], triphenylantimony dibenzoate (7) [2c], triphenylantimony ditosylate (8) [22] and triarylbismuthanes such as 18b [23], 18c [23], 18d [23] were prepared according to the reported procedures, and others were purchased from Tokyo Kasei Kogyo Co., Ltd., Japan.…”

Synthesis and structure of tri- and tetraphenylantimony aroxides: Ph3Sb[OC6H3(Br2-2,6)(Me-4)]2 AND Ph4SbOC6H3Br2-2,6, Me-4

“…It is known that redistribution of organic radicals between pentaphenylantimony and symmetrical derivatives of antimony with the general formula Ph 3 SbX 2 leads to formation of the single organoantimony compound with the general formula Ph 4 SbX, yielding up to 99 % [1][2][3][4][5][6]. This reaction is of universal character, since it is valid for compounds containing substituents (X) of various nature, but for tetraphenylantimony aroxides it has been demonstrated by one example only [5].…”