[1] In October 2003, thirteen major wildfires in southern California burned more than 300,000 hectares of mainly chaparral biome. High-precision in situ trace gas and particle measurements of the wildfire plumes in La Jolla, California, showed a high degree of correlation among carbon dioxide (CO 2 ), methane (CH 4 ), nonmethane hydrocarbons, and methyl halide mixing ratios, as well as with particle number concentrations (10-300 nm and 500-2500 nm aerodynamic diameter). Aerosol time-of-flight mass spectrometry of individual aerosol particles (50-2500 nm range) showed that 70-85% had typical biomass burning signatures (levoglucosan coupled with potassium). Only 5-18% of particles in the 50-300 nm range had vehicle signatures. Molar trace gas enhancement ratios (ERs) versus ethane and CO 2 were calculated and showed a narrow age distribution, consistent with the short distance from the wildfires. ERs for N 2 O and CH 3 CCl 3 versus CO 2 were determined, but correlations were poor. No significant CH 2 Cl 2 or CHCl 3 emissions were detected. CO 2 emissions from the nearby Cedar fire were estimated both with a simple Lagrangian atmospheric transport model and a burned area approach and extrapolated to 11 Tg CO 2 for the total burned area in southern California. Total CO 2 , CH 4 , C 2 -hydrocarbons, benzene, toluene, methyl chloride, methyl iodide, and PM 2.5 emissions were $0.2-3.5% of yearly global extratropical forest fire emissions and more than 28% of CH 4 , C 6 H 6 , and PM 2.5 2003 San Diego and South Coast Air Basins anthropogenic emissions. Particle distributions and single particle chemistry are discussed. PM 2.5 considerably exceeded the EPA short-term exposure limit.