“…Therefore, hot electron generation can be used for applications in photodetection, − photochemistry, − and photovoltaics. , For a metal–semiconductor configuration, the high energy electrons generated from the nonradiative decay of surface plasmons in a metal can contribute to a detectable photocurrent when they overcome the Schottky barrier. This has been experimentally investigated in systems with both wide-gap and conventional semiconductors, such as Au–Al 2 O 3 , and Au–Si. ,, HEs are also favorable for photochemistry, since they can contribute to chemical reactions through an indirect energy transition occurring through the carrier injection from metal to molecular species. To date, tremendous research effort has been directed to the use of HEs for water splitting, − ,− H 2 dissociation, ,,, H 2 production from ethanol, ,, and CO 2 reduction. , However, the short relaxation times and relatively small populations of HEs excited in plasmonic materials hinder their application in photodetection and photocatalysis.…”