Local bifurcations of stationary points and limit cycles have successfully been characterized in terms of the critical exponents of these solutions. Lyapunov exponents and their associated covariant Lyapunov vectors have been proposed as tools for supporting the understanding of critical transitions in chaotic dynamical systems. However, it is in general not clear how the statistical properties of dynamical systems change across a boundary crisis during which a chaotic attractor collides with a saddle.This behavior is investigated here for a boundary crisis in the Lorenz flow, for which neither the Lyapunov exponents nor the covariant Lyapunov vectors provide a criterion for the crisis. Instead, the convergence of the time evolution of probability densities to the invariant measure, governed by the semigroup of transfer operators, is expected to slow down at the approach of the crisis. Such convergence is described by the eigenvalues of the generator of this semigroup, which can be divided into two families, referred to as the stable and unstable Ruelle-Pollicott resonances, respectively. The former describes the convergence of densities to the attractor (or escape from a repeller) and is estimated from many short time series sampling the phase space. The latter is responsible for the decay of correlations, or mixing, and can be estimated from a long times series, invoking ergodicity.It is found numerically for the Lorenz flow that the stable resonances do approach the imaginary axis during the crisis, as is indicative of the loss of global A. Tantet · V. Lucarini 2 Alexis Tantet et al. stability of the attractor. On the other hand, the unstable resonances, and a fortiori the decay of correlations, do not flag the proximity of the crisis, thus questioning the usual design of early warning indicators of boundary crises of chaotic attractors and the applicability of response theory close to such crises.It is a problem of fundamental relevance in mathematical, natural, and applied sciences to understand under which conditions a system may undergo abrupt changes under perturbation and, if so, predict when these changes will occur. Much of our understanding of such transitions comes from the bifurcation theory of autonomous dynamical systems [1,2,3], with extensions to nonautonomous [4] and random [5] dynamical systems. In particular, local bifurcations, taking place for example when a stationary point or a limit cycle loses stability, are characterized by the critical exponents of these invariant sets. They yield a local measure of the relaxation rate of trajectories to these sets. As the latter become less stable, these exponents approach zero, resulting in the slowing down of the convergence of trajectories to the attractor. This critical slowing down has allowed to design early-warning signals of critical transitions by monitoring the rate of decay of correlations [6], peaks in power spectra [7], or of recovery from perturbations [8]. See [9], for a review, and [10] for applications to climate science.Most physica...