We give a precise connection between combinatorial Dyson-Schwinger equations and log-expansions for Green's functions in quantum field theory. The latter are triangular power series in the coupling constant α and a logarithmic energy scale L -a reordering of terms as G(α, L) = 1± j≥0 α j H j (αL) is the corresponding log-expansion. In a first part of this paper, we derive the leading-log order H 0 and the next-to (j) -leading log orders H j from the Callan-Symanzik equation. In particular, H j only depends on the (j + 1)-loop β-function and anomalous dimensions. For the photon propagator Green's function in quantum electrodynamics (and in a toy model, where all Feynman graphs with vertex sub-divergences are neglected), our formulas reproduce the known expressions for the next-to-next-to-leading log approximation in the literature. In a second part of this work, we review the connection between the Callan-Symanzik equation and Dyson-Schwinger equations, i.e. fixed-point relations for the Green's functions. Combining the arguments, our work provides a derivation of the log-expansions for Green's functions from the corresponding Dyson-Schwinger equations.