2008
DOI: 10.1134/s1995078008050054
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Aggregative stability and polydispersity of silver nanoparticles prepared using two-phase aqueous organic systems

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Cited by 26 publications
(8 citation statements)
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“…Separation and hydrophobization is due to the formation of an alkanethiol monolayer which is located in a non-polar environment. Brust and Schiffrin used toluene as the non-polar medium, and tetra-n-alkylammonium was used as the interfacial carrier [122]. The synthesis of silver nanoparticles by the Brust-Schiffrin method is also possible [122].…”
Section: Brust-schiffrin Methodsmentioning
confidence: 99%
“…Separation and hydrophobization is due to the formation of an alkanethiol monolayer which is located in a non-polar environment. Brust and Schiffrin used toluene as the non-polar medium, and tetra-n-alkylammonium was used as the interfacial carrier [122]. The synthesis of silver nanoparticles by the Brust-Schiffrin method is also possible [122].…”
Section: Brust-schiffrin Methodsmentioning
confidence: 99%
“…The interface between the two liquids and the intensity of inter-phase transport between two phases, which is mediated by a quaternary alkyl-ammonium salt, affect the rate of interactions between metal precursors and reducing agents. Metal clusters formed at the interface are stabilized, due to their surface being coated with stabilizer molecules occurring in the non-polar aqueous medium, and transferred to the organic medium by the inter-phase transporter (Krutyakov et al 2008). One of the major disadvantages of this method is the use of highly deleterious organic solvents.…”
mentioning
confidence: 99%
“…Silver nanoparticles were prepared by injecting them with various rates at high temperature up to 100 °C [17]. Microemulsion techniques are effective to synthesize uniform and size controllable silver nanoparticles [18]. The metal precursor and the reducing agent are in two immiscible phases aqueous organic-systems.…”
Section: Silver Nanoparticles and Their Propertiesmentioning
confidence: 99%