Advances in transition-metal catalyzed thioetherification reactions of aromatic compounds

Ghaderi, Arash

doi:10.1016/j.tet.2016.06.067

Cited by 76 publications

(30 citation statements)

References 121 publications

(61 reference statements)

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“…In this regards, we are reporting a new complex of Cu I on modified boehmite nanoparticles as efficient and reusable catalyst for the synthesis of sulfides and diaryl ethers via C−S and C−O cross coupling reactions. Because sulfides and diaryl ethers are starting material for the synthesis of organic compounds, drugs, and biological materials . Also, sulfides are starting materials for the synthesis of sulfoxides and sulfones …”

Section: Introductionmentioning

confidence: 94%

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New Complex of Copper on Boehmite Nanoparticles as Highly Efficient and Reusable Nanocatalyst for Synthesis of Sulfides and Ethers

Ghorbani‐Choghamarani

Heidarnezhad

Tahmasbi

2019

ChemistrySelect

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Boehmite is a cubic orthorhombic structure of aluminum oxide hydroxide, which prepared via addition of sodium hydroxide solution to an aluminum nitrate solution at room temperature. In this work, the surface of boehmite nanoparticles (BNPs) modified by 3‐choloropropyltrimtoxysilane (3‐CPTMS), then reacted with N,N,N′,N′‐tetraethyldiethylentriamine (TEDETA). Eventually, CuI immobilized on modified boehmite (CuI‐TEDETA@BNPs). Structure of this catalyst was characterized using FT‐IR, TEM, SEM, EDS, TGA, and AAS techniques. Finally, the catalytic activity of CuI‐TEDETA@BNPs was studied for the synthesis of ethers and sulfides. All ethers and sulfides were obtained in high yields, which reveals the high activity of described catalyst. This catalyst was reused for several times without significant loss of its catalytic efficiency. Recovered catalyst was characterized by SEM and FT‐IR techniques, which shown a good agreement with fresh catalyst. Also, heterogeneity and stability of CuI‐TEDETA@BNPs confirmed by hot filtration test.

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Section: Introductionmentioning

confidence: 94%

“…Because sulfides and diaryl ethers are starting material for the synthesis of organic compounds, drugs, and biological materials. [46][47][48][49][50][51][52][53][54][55] Also, sulfides are starting materials for the synthesis of sulfoxides and sulfones. [56]…”

Section: Introductionmentioning

confidence: 99%

New Complex of Copper on Boehmite Nanoparticles as Highly Efficient and Reusable Nanocatalyst for Synthesis of Sulfides and Ethers

Ghorbani‐Choghamarani

Heidarnezhad

Tahmasbi

2019

ChemistrySelect

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“…The first report on C−S cross‐coupling reaction was described by Migita et al . in whose scenario the authors used a palladium catalyst (Pd(Ph 3 ) 4 ).…”

Section: Introductionmentioning

confidence: 99%

“…The first report on CÀS cross-coupling reaction was described by Migita [10] et al in whose scenario the authors used a palladium catalyst (Pd(Ph 3 ) 4 ). Several methods have been developed for the formation of the carbon-sulfur bond using catalytic systems composed of Pd, [11] Cu, [12] Ni, [13] and Fe.…”

Section: Introductionmentioning

confidence: 99%

C-S Cross-Coupling Reaction Using a Recyclable Palladium Prolinate Catalyst under Mild and Green Conditions

et al. 2017

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“…Therefore, a search for undiscovered sulfur source that could be applicable to organic sulfur chemistry is imperative, and extensive efforts have been devoted for development of molecular 23 transformations utilizing a novel sulfur source by many research groups thus far [1][2][3][4][5][6]. In this context,…”

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confidence: 99%

Indium-Catalyzed Direct Conversion of Lactones into Thiolactones Using a Disilathiane as a Sulfur Source

Ogiwara

Takano

Horikawa

et al. 2018

Preprint

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Indium-catalyzed reaction of lactones and a disilathiane leading to thiolactones is 10 described. The direct synthesis of thiolactones from lactones with an appropriate sulfur source is 11 one of the most attractive approaches in organic and pharmaceutical chemistry. In this context, we 12found an indium-catalyzed direct conversion of lactones into thiolactones in the presence of 13 elemental sulfur and a hydrosilane via formation of the disilathiane in-situ. On the basis of the 14 previous reaction, the application utilizing the disilathiane as a sulfur source was performed herein 15for the efficient synthesis of a variety of thiolactone derivatives from lactones by an indium-catalyst. 16

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Advances in transition-metal catalyzed thioetherification reactions of aromatic compounds

Cited by 76 publications

References 121 publications

New Complex of Copper on Boehmite Nanoparticles as Highly Efficient and Reusable Nanocatalyst for Synthesis of Sulfides and Ethers

New Complex of Copper on Boehmite Nanoparticles as Highly Efficient and Reusable Nanocatalyst for Synthesis of Sulfides and Ethers

C-S Cross-Coupling Reaction Using a Recyclable Palladium Prolinate Catalyst under Mild and Green Conditions

Indium-Catalyzed Direct Conversion of Lactones into Thiolactones Using a Disilathiane as a Sulfur Source

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