Advanced ferroferric oxide-based composites for lithium-ion battery: Recent developments and future perspectives

Jiang, Huiyu; Mu, Qin; Kimura, Hideo; Liu, Rui; Yang, Wenyue; Liu, Liyuan; Du, Wei; Hou, Chuanxin

doi:10.1016/j.pnsc.2023.12.017

Cited by 12 publications

(3 citation statements)

References 95 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…Carbon nanomaterials such as carbon nanotubes (CNTs) or graphene have attracted significant attention due to their exceptional electron mobility, high ampacity, and low density . However, the overall performance of pure carbon cannot meet the application requirements, combining carbon with metals and metal oxides usually turns out excellent effects, like catalysis, lithium storage, , and supercapacitors. , The theoretical current carrying ability of carbon nanotubes , and graphene has been reported to be ∼10 9 and ∼10 8 A/cm 2 , respectively, which is two to 3 orders of magnitude higher than that of pure Cu. In general, it is believed that there exists an inverse relationship between conductivity and ampacity, with metals possessing higher conductivities while nanocarbons possessing greater ampacities .…”

Section: Introductionmentioning

confidence: 99%

Three Dimensional Graphene/Copper Dual Networks as Composite Conductors with Enhanced Current Carrying Capacity

Chen,

Zhao,

Wen

et al. 2024

ACS Appl. Nano Mater.

View full text Add to dashboard Cite

The resolution of electronic devices toward miniaturization and lightweight puts forward requirements for current carrying capacity and density of conductors. Composite conductors consisting of copper as the matrix material and nanocarbon as the filler have aroused great interest, which revealed apparently enhanced ampacity and low density compared to pure Cu. In this study, three-dimensional laser-induced graphene (LIG) was used as the nanocarbon filler to improve the ampacity of Cu by a two-step electrodeposition method. After organic Cu seeding and a subsequent aqueous densification process, a uniformly dispersed graphene/copper dual network composite was obtained. This composite exhibits an enhanced ampacity of 1.34 × 10 5 A/cm 2 (increased 76% compared with pure Cu) and a low density of 3.27 g/cm 2 (36.5% of pure Cu). Benefiting from the patterning preparation of laser direct writing technology, this method enables the creation of conductive lines with various desired carves. Thus, this graphene−Cu composite conductor would be useful to overcome the current limit in Cu conductors and cables for lightweight high-power electrical energy transfer devices.

show abstract

Section: Introductionmentioning

confidence: 99%

Three Dimensional Graphene/Copper Dual Networks as Composite Conductors with Enhanced Current Carrying Capacity

Chen,

Zhao,

Wen

et al. 2024

ACS Appl. Nano Mater.

View full text Add to dashboard Cite

show abstract

“…The primary approaches for extracting valuable metals from SLIBs include pyrometallurgical, hydrometallurgical, and integrated processes. , In addition to traditional recycling techniques, there is a growing focus on exploring the utilitarian value of SLIB cathodes as raw materials . Recent research has illustrated that diverse microorganisms can effectively catalyze the reduction or conversion of metal ions in the leachate from waste materials (such as Ag + , Cr 6+ , Au 3+ , and Pb 2+ ) into biobased materials. , The exploration of microbial upgrading for cathodes of SLIBs is still in the early stages.…”

Section: Introductionmentioning

confidence: 99%

Regenerating Spent Lithium-Ion Battery Cathodes as Dual-Functional Biocatalysts for Highly-Efficient Oxygen and Hydrogen Evolution Using Aspergillus niger Soluble Extracellular Polymers

Ge,

Kang,

et al. 2024

ACS Sustainable Chem. Eng.

View full text Add to dashboard Cite

The lithium-ion battery market is rapidly expanding but lacks recycling for spent lithium-ion battery (SLIB) cathodes, overlooking their potential as valuable raw materials. Herein, we present a novel win−win bioregulation strategy to repurpose SLIB cathodes into dual-functional biocatalysts for oxygen and hydrogen evolution reactions (OER and HER) using Aspergillus niger soluble extracellular polymers. In the recycled SLIB cathode ink, 85% of cobalt has been regenerated as catalysts. Simultaneously, valuable materials such as graphite and cobalt, which have not been regenerated, are separated and stored. Integrating characterization and theoretical calculations reveals that bioregulation enhances the hydrophilicity of 70-Bio-Co/GOs and enables biological nitrogen doping. Compared to the catalyst lacking bioregulation, we observe a 0.27 eV elevation in the d-band center and identify a metallic-like electron distribution around the Fermi level. Consequently, compared with other studies, 70-Bio-Co/GO exhibits a slight superiority in OER (η 10 of 251 mV), HER (η 10 of 110 mV), and overall water splitting (25 mA cm −2 with a potential of 1.641 V) performance, along with stability (98 h). Overall, we investigated the potential of bioregulation technology for regenerating SLIBs.

show abstract

“…The binder-less approach not only streamlines the electrode fabrication process but also contributes to the overall sustainability of flexible supercapacitor technology [33][34][35][36], and MXene (Ti 3 C 2 T x ) ink has been used as an additive/binder-less coating for batteries and direct coating of electrodes [37][38][39][40]. Furthermore, this study explored advancements in energy storage devices, including the integration of Co 3 O 4 nanoparticles with carbon composites for enhanced Li-ion storage capabilities, as well as the development of N-doped carbon spheres with MnO 2 composites tailored for high-energy supercapacitor applications [41][42][43].…”

Section: Introductionmentioning

confidence: 99%

Binder-Free Two-Dimensional Few-Layer Titanium Carbide MXene Ink for High-Performance Symmetric Supercapacitor Device Applications

Thirumal,

Rajkumar,

Kim

et al. 2024

Crystals

View full text Add to dashboard Cite

A heightened interest in developing MXene (Ti3C2Tx) for energy storage is evident in binder-free MXene ink being directly applied to current collector Ni-foam. Moreover, 2D titanium carbide MXene, with a few layers of nanostructure, has been prepared for symmetric supercapacitor device applications. As-prepared MXene nanosheets exist in two forms: dried powder and ink, achieved through wet-chemical etching and dimethyl sulfoxide delamination from the MAX (Ti3AlC2) phase. This comparative study of electrode devices involves (i) MX-dry powder with binder/additive electrodes and (ii) binder-free MXene inks with directly applied MX-conductive inks. The surface morphological images of pure MX-powder/ink display few layers, and material analysis reveals the good crystalline nature of delaminated MXene (Ti3C2Tx) inks. The electrochemical symmetric supercapacitor device performances of pure MXene powder and binder-free directly applied/coated MXene (Ti3C2Tx) ink, in terms of cyclic voltammetry (CV) and impedance spectroscopy (EIS), exhibit galvanostatic charge–discharge (GCD) curves that show high specific capacitance (Csp) at 105.75 F/g at a current density of 1 A/g. A comparison of active material electrodes demonstrated excellent cycle stability. Hence, in this work, we confirmed the superior capacitive behavior of binder-free MXene ink (MX-I) compared to conductive additives with polymeric binders included in MXene electrodes.

show abstract

Advanced ferroferric oxide-based composites for lithium-ion battery: Recent developments and future perspectives

Cited by 12 publications

References 95 publications

Three Dimensional Graphene/Copper Dual Networks as Composite Conductors with Enhanced Current Carrying Capacity

Three Dimensional Graphene/Copper Dual Networks as Composite Conductors with Enhanced Current Carrying Capacity

Regenerating Spent Lithium-Ion Battery Cathodes as Dual-Functional Biocatalysts for Highly-Efficient Oxygen and Hydrogen Evolution Using Aspergillus niger Soluble Extracellular Polymers

Binder-Free Two-Dimensional Few-Layer Titanium Carbide MXene Ink for High-Performance Symmetric Supercapacitor Device Applications

Contact Info

Product

Resources

About