Advanced energetic materials: novel strategies and versatile applications

Zlotin, Sergei G.; Churakov, A. M.; Egorov, Mikhail P.; Ферштат, Леонид Л.; Klenov, M. S.; Kuchurov, Ilya V.; Махова, Н. Н.; Smirnov, G. A.; Tomilov, Yury V.; Tartakovsky, Vladimir A.

doi:10.1016/j.mencom.2021.11.001

Cited by 76 publications

(30 citation statements)

References 148 publications

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“…[1][2][3][4] One of the main goals in the development of novel energetic materials is the creation of compounds with increased detonation performance. [5][6][7] This oen is at odds with the other main goal of increased stability against thermal and mechanical stimuli. [8][9][10] Balancing these two goals motivates most of the synthetic efforts in new energetic compounds.…”

Section: Introductionmentioning

confidence: 99%

Progress and performance of energetic materials: open dataset, tool, and implications for synthesis

2022

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Section: Introductionmentioning

confidence: 99%

Progress and performance of energetic materials: open dataset, tool, and implications for synthesis

2022

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“…Performance and sensitivity of currently used high-energy compounds (TNT: 2,4,6-trinitrotoluene, RDX: 1,3,5-trinitro-1,3,5-triazinane, PETN: pentaerythritol tetranitrate) are usually unbalanced, while their ecological and toxicological profiles are unfavorable. In this regard, preparation of novel eco-friendly energetic materials with high nitrogen content and acceptable safety requirements remains urgent ( Kuchurov et al, 2017 ; Zlotin et al, 2021 ).…”

Section: Introductionmentioning

confidence: 99%

Novel family of nitrogen-rich energetic (1,2,4-triazolyl) furoxan salts with balanced performance

et al. 2022

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Nitrogen-rich energetic materials comprised of a combination of several heterocyclic subunits retain their leading position in the field of materials science. In this regard, a preparation of novel high-energy materials with balanced set of physicochemical properties is highly desired. Herein, we report the synthesis of a new series of energetic salts incorporating a (1,2,4-triazolyl) furoxan core and complete evaluation of their energetic properties. All target energetic materials were well characterized with IR and multinuclear NMR spectroscopy and elemental analysis, while compound 6 was further characterized by single-crystal X-ray diffraction study. Prepared nitrogen-rich salts have high thermal stability (up to 232°C), good experimental densities (up to 1.80 g cm−3) and high positive enthalpies of formation (344–1,095 kJ mol−1). As a result, synthesized energetic salts have good detonation performance (D = 7.0–8.4 km s−1; p = 22–32 GPa), while their sensitivities to impact and friction are quite low.

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“…[5][6][7][8][9][10][11][12] Over the last few decades, search for novel high-energy structures has been focused on HEDMs incorporating various heterocyclic frameworks. 13,14 In contrast to nitroaromatic and carbocyclic explosives, such HEDMs have good ecological profiles and possess high positive enthalpies of formation. 15 In this sense, 1,2,5-oxadiazole N-oxide (furoxan) attracts significant attention due to a high positive enthalpy of formation (198.5 kJ mol −1 ) and a huge nitrogen-oxygen content present within the core.…”

Section: Introductionmentioning

confidence: 99%