Adsorption of surfactants and proteins at fluid interfaces

Fainerman, V. B.; Lucassen-Reynders, E. H.; Miller, R.

doi:10.1016/s0927-7757(98)00585-8

Cited by 224 publications

(262 citation statements)

References 91 publications

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“…The theoretical two states models were used to describe the equilibrium surface tension and adsorption of surfactants and were described in earlier elsewhere [6,[7][8][9][10]. Therefore, only the main equations for each applied model are given below.…”

Section: Reorientation Modelmentioning

confidence: 99%

“…Assuming ideal enthalpy of mixing of the surface layer, the equations of state and adsorption isotherm read [7][8][9]:…”

Section: Reorientation Modelmentioning

confidence: 99%

“…In [9,[20][21][22][23] such kind of phase transitions were treated using the quasi-chemical approach based on the analysis of chemical potentials of the components in the surface layer. When aggregates are formed at the surface (interface), the equilibrium between monomers and n-mers can be described by the following equation [9,20]:…”

Section: Aggregation Of Adsorbed Moleculesmentioning

confidence: 99%

“…When aggregates are formed at the surface (interface), the equilibrium between monomers and n-mers can be described by the following equation [9,20]:…”

Section: Aggregation Of Adsorbed Moleculesmentioning

confidence: 99%

“…Then the equation of state for surface layers of aggregating surfactants and the adsorption isotherm of monomers becomes [9,:…”

Section: Aggregation Of Adsorbed Moleculesmentioning

confidence: 99%

See 4 more Smart Citations

Equilibrium and dynamic surface properties of trisiloxane aqueous solutions. Part 2. Theory and comparison with experiment

Ritacco

Fainerman

Ortega

et al. 2010

Colloids and Surfaces A: Physicochemical and Engineering Aspect

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Section: Reorientation Modelmentioning

confidence: 99%

“…Assuming ideal enthalpy of mixing of the surface layer, the equations of state and adsorption isotherm read [7][8][9]:…”

Section: Reorientation Modelmentioning

confidence: 99%

Section: Aggregation Of Adsorbed Moleculesmentioning

confidence: 99%

“…When aggregates are formed at the surface (interface), the equilibrium between monomers and n-mers can be described by the following equation [9,20]:…”

Section: Aggregation Of Adsorbed Moleculesmentioning

confidence: 99%

“…Then the equation of state for surface layers of aggregating surfactants and the adsorption isotherm of monomers becomes [9,:…”

Section: Aggregation Of Adsorbed Moleculesmentioning

confidence: 99%

See 3 more Smart Citations

Equilibrium and dynamic surface properties of trisiloxane aqueous solutions. Part 2. Theory and comparison with experiment

Ritacco

Fainerman

Ortega

et al. 2010

Colloids and Surfaces A: Physicochemical and Engineering Aspect

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Biomimetic Membranes

2010

Molecular Assembly of Biomimetic Systems

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Effect of protein penetration into phospholipid monolayers: morphology and structure . Colloids Surf. A , 168 , 287 -296 . 40 Li , J.B. , Kretzschmar , G. , Miller , R. , and M ö hwald , H. ( 1999 ) Viscoelasticity of phospholipid layers at different fl uid interfaces . Colloids Surf. A , 149 , 491 -497 . 41 Li , J.B. , Miller , R. , and M ö hwald , H. ( 1996 ) Phospholipid monolayers and their dynamic interfacial behaviour studied by axisymmetric drop shape analysis . Axisymmetrical drop shape analysis as a fi lm balance . Colloids Surf. A , 88 , 51 -58 . 44 Li , J.B. , Miller , R. , Vollhardt , D. , Weidemann , G. , and M ö hwald , H. ( 1996 ) Isotherms of phospholipid monolayers measured by a pendant drop technique . Colloid Polym. Sci. , 274 , 995 -999 . 45 Li , J.B. , Miller , R. , and M ö hwald , H. ( 1996 ) Characterisation of phospholipid

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Thermodynamic aspects of the bovine serum albumin adsorption onto N,N′‐ diethylaminoethyl dextran microbeads

Can

Güner

2005

J of Applied Polymer Sci

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Adsorption of proteins on solid surfaces is widely studied because of its importance in various biotechnological, medical, and technical applications, e.g., biosensor cardiovascular implants and chromatography. Adsorption thermodynamics has been studied on the microbeads of N,NЈ-diethylaminoethyl (DEAE) dextran anion exchanger for bovine serum albumin at 25, 30, 35 40, and 45°C. As a result some thermodynamic parameters like Freundlich constants, thermodynamic equilibrium constant (K D ), standard free energy changes (⌬G assoc ), standard entropy changes (⌬S assoc ), and standard enthalpy change (⌬H assoc ) have been evaluated. Using the linear Van't Hoff plot, the ⌬H assoc value of the system for the interaction of BSA adsorbed crosslinked DEAE dextran microbeads was determined as 12.5 kJ/mol.

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Adsorption of surfactants and proteins at fluid interfaces

Cited by 224 publications

References 91 publications

Equilibrium and dynamic surface properties of trisiloxane aqueous solutions. Part 2. Theory and comparison with experiment

Equilibrium and dynamic surface properties of trisiloxane aqueous solutions. Part 2. Theory and comparison with experiment

Biomimetic Membranes

Thermodynamic aspects of the bovine serum albumin adsorption onto N,N′‐ diethylaminoethyl dextran microbeads

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