1997
DOI: 10.1006/jcis.1996.4739
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Adsorption Mechanism of Gallium(III) and Indium(III) onto γ-Al2O3

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Cited by 25 publications
(12 citation statements)
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References 14 publications
(20 reference statements)
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“…Trivalent cation hydrolysis is also consistent with some pressure-jump kinetic data (Lin et al, 1997). Hiemstra and van Riemsdijk (2002) propose that adsorbed cations are either more or less prone to hydrolysis depending on the degree of distortion of their coordination environment relative to homogeneous solutions.…”
mentioning
confidence: 52%
See 1 more Smart Citation
“…Trivalent cation hydrolysis is also consistent with some pressure-jump kinetic data (Lin et al, 1997). Hiemstra and van Riemsdijk (2002) propose that adsorbed cations are either more or less prone to hydrolysis depending on the degree of distortion of their coordination environment relative to homogeneous solutions.…”
mentioning
confidence: 52%
“…Previous investigations have noted that the adsorption constants of metal cations are linearly correlated with the corresponding aqueous hydrolysis constants at room temperature (e.g., Dzombak and Morel, 1990;Kosmulski, 1997b;Lin et al, 1997). The recent experimental studies of aqueous Nd 3ϩ hydrolysis conducted by Klungness and Byrne (2000) (27) which is of the same form as the corresponding solution first hydrolysis constant.…”
Section: Temperature Dependencementioning
confidence: 94%
“…The hydrolysis of trivalent species occurs readily in aqueous solutions at high pH (pH > 7, Wood, 1990b;Klungness and Byrne, 2000;Wood et al, 2002). In addition, the hydrolysis of adsorbed trivalent cations is frequently considered in surface complexation models (James and Healy, 1972;Dzombak and Morel, 1990;Stumm, 1992;Hiemstra and van Riemsdijk, 2007), and some pressure-jump kinetic data suggest hydrolysis of trivalent cations (Lin et al, 1997).…”
Section: Yttrium and Neodymium Surface Complexationmentioning
confidence: 99%
“…At low metal concentrations, metal adsorption onto hydrous solids is mainly a surface coordination process, which can be modeled thermodynamically as a complexation reaction between surface sites and adsorbates [1]. In the past decades, surface complex formation models (SCFM) have been shown to be capable of describing metal ion adsorption onto solid surfaces, such as oxides, activated carbon, soils, concrete, sludge, and sediments [2][3][4][5][6][7][8][9][10][11][12][13]. While the adsorption of metals onto soil has been extensively studied, investigation of adsorption mechanisms in response to variety of binding energies has received little attention.…”
Section: Introductionmentioning
confidence: 99%