Abstract:The field of adhesion has revealed a significant impact on numerous amount of applications such as wound healing, drug delivery, electrically conductive adhesive, dental adhesive, and wood industry. Nanotechnology has...
“…52,54 Moreover, some nanomaterials can be easily removed due to their undesirable adhesive performance to biological tissue. 55 Representative nanomaterials commonly used in NNPHs for wound healing mainly include carbon-based, [56][57][58][59][60][61][62] metal-based, [63][64][65][66][67][68][69][70] MXene-based [71][72][73][74][75] and siliconbased [76][77][78] nanomaterials, as shown in Table 2 and Fig. 3.…”
Skin injury occurs due to acute trauma, chronic trauma, infection, and surgical intervention, which can result in severe dysfunction and even death in humans. Therefore, clinical intervention is critical...
“…52,54 Moreover, some nanomaterials can be easily removed due to their undesirable adhesive performance to biological tissue. 55 Representative nanomaterials commonly used in NNPHs for wound healing mainly include carbon-based, [56][57][58][59][60][61][62] metal-based, [63][64][65][66][67][68][69][70] MXene-based [71][72][73][74][75] and siliconbased [76][77][78] nanomaterials, as shown in Table 2 and Fig. 3.…”
Skin injury occurs due to acute trauma, chronic trauma, infection, and surgical intervention, which can result in severe dysfunction and even death in humans. Therefore, clinical intervention is critical...
“…These functionalities will enable them to combine with silver flakes in thermoset epoxies as complementary conductive fillers to create high-performance conductive adhesives (ECAs). Over the past decade, ECAs have emerged as a direct and scalable replacement for the hazardous Sn–Pb solder used in traditional interconnect processes for electronic devices. − Usually, to improve the conductivity of the ECAs, it is necessary to introduce silver nanoparticles as complementary conductive fillers to disperse among the silver flakes of the ECAs to enhance their performance. − These silver nanoparticles could be effectively replaced by cheap and highly stable Sn nanoparticles in this work. By adding 7 wt % Sn nanoparticles as complementary conductive fillers, the resistivity of the ECAs can be reduced to 1/6000 of that of the ECAs filled with only the same mass ratio of silver flakes, exhibiting its great potential in future electronics.…”
Tin (Sn) metallic material is one of the best-known metals and has been extensively studied due to its ease of processing, low melting point, and low cost. However, it is still challenging to synthesize high-processing performance and antioxidant Sn nanoparticles with tunable sizes. This research reported a facile, easy-to-scale-up polyol-mediated synthesis of Sn nanoparticles assisted by sodium citrates as a capping agent. The presence of citrate capping facilitated uniform nucleation of Sn nanoparticles and enhanced their antioxidant capacity and dispersion properties. These nanoparticles can remain stable against oxidation for more than 270 days in an ambient atmosphere, even under continuous heating at 200 °C for over 12 h. The citrate capping also inhibits interparticle agglomeration and allows the preparation of high-quality suspensions in water and many conventional organics. Moreover, efficient size tuning over a wide range (60 nm−1 μm) can be achieved simply by changing the Sn 2+ precursor concentrations. The above-mentioned antioxidant capacity and processability allow them to combine with silver flakes in thermosetting epoxy resin as complementary conductive fillers effectively, creating conductive pathways among the silver flakes to obtain high-performance electrically conductive adhesives (ECAs). By adding Sn nanoparticles as complementary conductive fillers, the resistivity of the ECAs can be reduced to 1/ 6000 of that of the ECAs filled with only the same mass ratio of silver flakes, exhibiting its great potential in future electronics.
“…Many animals have evolved unique adhesion organs to adapt themselves to complex natural environments. − The remarkable adhesion abilities originate from the specialized micro/nanostructures and/or chemical components of these organisms. − Geckos are the most widely studied animals and are considered to rely on the setae (fibrillar array) on their toes to generate strong shear adhesion and friction. ,− Meanwhile, the asymmetric structure of setae, which includes the slanted geometry and the spatular ends, besides the special upwards bending of toes, ensures easy detachment. − Therefore, both pillar and anisotropic structures are important for achieving strong and reversible adhesion. , Inspired by the fibrillar structure in geckos, bioinspired adhesives composed of an array of micro/nanopillars have been constructed for diverse applications, including medical tapes, sporting goods, climbing robots, semiconductor carriers, and many others. − …”
Bioinspired structured adhesives
have promising applications in
the fields of robotics, electronics, medical engineering, and so forth.
The strong adhesion and friction as well as the durability of bioinspired
hierarchical fibrillar adhesives are essential for their applications,
which require fine submicrometer structures to stay stable during
repeated use. Here, we develop a bioinspired bridged micropillars
array (BP), which realizes a 2.18-fold adhesion and a 2.02-fold friction
as compared to that of poly(dimethylsiloxane) (PDMS) original
micropillar arrays. The aligned bridges offer BP strong anisotropic
friction. The adhesion and friction of BP can be finely regulated
by changing the modulus of the bridges. Moreover, BP shows strong
adaptability to surface curvature (ranging from 0 to 800 m–1), excellent durability over 500 repeating cycles of attachment/detachment,
and self-cleaning ability. This study presents a novel approach for
designing robust structured adhesives with strong and anisotropic
friction, which may find applications in areas such as climbing robots
and cargo transportation.
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