1981
DOI: 10.1002/app.1981.070261230
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Acyclic azoester modification of 1,4‐polybutadienes. II. Green strength and tack properties

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“…Because the plateau modulus is not strictly independent of frequency, a quantitative estimation of 44, the molecular weight between entanglements, cannot be made directly from the data of Figure 1. An estimate of the shear modulus due to the entanglement network, G,, can be obtained by assuming a uniform spacing of these couplings, for which a phenomenological theory predicts7s8 G,, = G R/0.207 (1) where G'k designates the maximum value of the loss modulus in the terminal region.…”
Section: Of Interfacial Contactmentioning
confidence: 99%
“…Because the plateau modulus is not strictly independent of frequency, a quantitative estimation of 44, the molecular weight between entanglements, cannot be made directly from the data of Figure 1. An estimate of the shear modulus due to the entanglement network, G,, can be obtained by assuming a uniform spacing of these couplings, for which a phenomenological theory predicts7s8 G,, = G R/0.207 (1) where G'k designates the maximum value of the loss modulus in the terminal region.…”
Section: Of Interfacial Contactmentioning
confidence: 99%