Evidence of strain-induced phase separation in isopropyl azodicarboxylate modified polybutadiene

Hamed, G. R.; Shieh, C.-H.; Schulz, D. N.

doi:10.1007/bf00265239

Search citation statements

Order By: Relevance

Paper Sections

Select...

Strain-induced Glass Transition1

Citation Types

Supporting

Mentioning

Contrasting

Year Published

1984

2006

Publication Types

Select...

Article2

Relationship

Self Cite0

Independent2

Authors

Journals

Cited by 2 publications

(1 citation statement)

References 4 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…[102][103][104][105][106][107] The possibility also exists for a change in the phase morphology of multi-component rubbers due to strain. 108,109 These phenomena are not unique to elastomers: metal alloys 110 and ceramics 111 undergo solid-solid phase transitions as a result of mechanical stress. The effect serves as the mechanism for many shape-memory materials.…”

Section: Strain-induced Glass Transitionmentioning

confidence: 99%

Mechanical Behavior of Rubber at High Strain Rates

Roland

2006

Rubber Chemistry and Technology

View full text Add to dashboard Cite

Methods to obtain the mechanical response of rubber at high rates of strain are reviewed. These techniques include the extrapolation of low strain, low strain rate data, the limitations of which are discussed, extrapolations to elevated hydrostatic pressure, and direct determinations using split Hopkinson bar and drop weight testers, as well as miscellaneous methods. Some applications involving rubber at strain rates sufficient to induce a transition to the glassy state are described.

show abstract

Section: Strain-induced Glass Transitionmentioning

confidence: 99%

Mechanical Behavior of Rubber at High Strain Rates

Roland

2006

Rubber Chemistry and Technology

View full text Add to dashboard Cite

show abstract

The mechanism for enhanced autoadhesion in azoester‐modified polybutadienes

Roland¹,

Böhm²

1984

J of Applied Polymer Sci

View full text Add to dashboard Cite

The addition of IAD pendant groups to PB molecules results in a larger effective chain crosssectional area with consequent decrease in chain entanglements. This causes the rubber to be more complaint at low strains and strain rates. Simultaneously, the IAD structures give rise to polar and H‐bond interactions which cause the material to exhibit strong adhesion and to possess high green strength. As a result, the IAD‐PB is a relatively rare example of a synthetic polymer with good autoadhesive properties.

show abstract

Evidence of strain-induced phase separation in isopropyl azodicarboxylate modified polybutadiene

Cited by 2 publications

References 4 publications

Mechanical Behavior of Rubber at High Strain Rates

Mechanical Behavior of Rubber at High Strain Rates

The mechanism for enhanced autoadhesion in azoester‐modified polybutadienes

Contact Info

Product

Resources

About