Recently, smart windows based on polymer-dispersed liquid crystals (PDLCs) composites have garnered enormous interest owing to their electrically switchable properties. However, the low UV-shielding characteristics of these films limit their widespread application. Here, we reported novel PDLC composite films doped with functionalized TiO 2 nanoparticles (NPs) to enhance the UV-shielding efficiency. The TiO 2 NPs were chemically functionalized by 3-aminopropyltriethoxysilane (APTS) and 3-methacryloxypropyltrimethoxysilane (MPTS), respectively. Scanning electron microscopy (SEM) studies revealed that APTS functionalized TiO 2 NPs tended to cluster in the polymer network instead of liquid crystal droplets, and MPTS functionalized TiO 2 NPs were independently and uniformly dispersed in the polymer network. Particularly, optical studies showed that the TiO 2 (MPTS)/PDLC composite film can effectively shield 95.9% UV light at on-state, and 99.16% at off-state. Furthermore, compared to traditional PDLC film (without TiO 2 NPs), the total response time of the TiO 2 (MPTS)/PDLC film is reduced from 60.4 to 13.4 ms, and the contrast ratio (CR) was increased by more than twofold from 35.6 to 97.26.