Accurately metal-modulated bimetallic metal–organic frameworks as advanced trifunctional electrocatalysts

Abstract

The atomic-level metal-modulated MOFs as an advanced trifunctional electrocatalyst for oxygen evolution reaction, hydrogen evolution reaction and oxygen reduction reaction.

Recent progress in metal–organic frameworks (MOFs) for electrocatalysis

“…Since bimetallic MOFs have been widely used in the OER, the researchers speculate that the rational design of the structure of bimetallic MOFs can also play a role in improving their electrocatalytic oxygen reduction performance, considering 91 Reproduced with permission. 96 Copyright 2019, American Chemical Society.…”

“…95 Copyright 2019, Wiley-VCH; (g) schematic diagram of the CoNiMOF/rGO catalyst; (h) LSV curves of CoNi-MOF/rGO and other samples for ORR tests in O 2 -saturated 0.1 M KOH. Rotation rate: 1600 rpm 91. Reproduced with permission 96.…”

Recent advances in the metal–organic framework-based electrocatalysts for trifunctional electrocatalysis

“…The comparison of the various reported MOF-based electrocatalysts has been provided in Table 1 (including ref. 37, 49–89).…”

“…2a-c, respectively. 53 The importance has been given to the presence of both the co-ordinately unsaturated metal sites or the open metal sites (OMSs) at the ends and the co-ordinately saturated metal sites (CSMSs) in the middle, respectively. Two MOFs i.e., Ni-MOF and NiFe-MOF were synthesised which were named as Ni 3 -MOF and NiFe-MOF.…”

Atomic‐Level Interface Engineering for Boosting Oxygen Electrocatalysis Performance of Single‐Atom Catalysts: From Metal Active Center to the First Coordination Sphere

“…And the theoretical overpotential (ȵ) of the HER/OER/ORR as descriptors of trifunctional electrocatalytic activity, and the theoretical overpotential depending on the RDS in DFT (right). Reproduced with permission [74]. Copyright 2021, The Royal Society of Chemistry.…”