Lattice Boltzmann Method (LBM), newly developing technique of computational fluid dynamics, is coupled with solute and energy conservation equations to develop a macrosegregation simulation model (LBM-coupled model) with high computational efficiency. LBM does not require time-consuming calculations for correction of velocity and pressure of fluid in contrast to methods directly solving Navier-Stokes (NS) equation and, therefore, LBM is computationally efficient. In this study, the accuracy of the LBMcoupled model is investigated by calculating the steady state flows and by comparing the results with those of analytical solutions and a conventional model based on the NS equation. The results between them are almost identical with each other and it indicates that the accuracy of the LBM-coupled model is sufficiently high. Moreover, a macrosegregation simulation is carried out for a simple case where the macrosegregation emerges only by natural convection, by means of the LBM-coupled and conventional models. The LBM-coupled model yields almost the same result with the one of NS-based model. Importantly, however, the simulation of LBM-coupled model is about five times faster than the one of NS-based model.