A two-enzyme system in an amorphous metal–organic framework for the synthesis of <scp>d</scp>-phenyllactic acid

Wang, Yifeng; Sun, Xiaolong; Hu, Jiahuan; Guo, Qing; Zhang, Ping; Luo, Xi; Shen, Baolong; Fu, Yongqian

doi:10.1039/d3tb00126a

Cited by 3 publications

(1 citation statement)

References 43 publications

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“…By implementing the Vienna Ab Initio Simulation Package [29] , the generalized gradient approximation (GGA)/ Perdew-Burke-Ernzerhof (PBE) function was selected to calculate the exchange and correlation potentials [30] . A weak van der Waals interaction was considered by the DFT-D3 function [31] . The cutoff energy for the plane wave was 400 eV.…”

Section: Materials Characterization and Electrochemical Testsmentioning

confidence: 99%

Strong coordination interaction in amorphous Sn-Ti-ethylene glycol compound for stable Li-ion storage

Cai,

Liu,

et al. 2023

Energy Materials and Devices

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The Sn-Ti-EG electrode exhibits exceptional cyclic stability with high Li-ion storage capacities. Even after 700 cycles at a current density of 1.0 A g −1 , the anode maintains a capacity of 345 mAh g −1 . The unique bimetal organic structure of the Sn-Ti-EG anode and the strong coordination interaction between Sn/Ti and O within the framework effectively suppress the aggregation of Sn atoms, eliminating the usual pulverization of bulk Sn through volume expansion.

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Section: Materials Characterization and Electrochemical Testsmentioning

confidence: 99%

Strong coordination interaction in amorphous Sn-Ti-ethylene glycol compound for stable Li-ion storage

Cai,

Liu,

et al. 2023

Energy Materials and Devices

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Insight into Anionic Discrepancies in Bipolar Poly(Thionine) Organic Cathodes for Aqueous Zinc Ion Batteries

Zhan,

Wang,

Zhong

et al. 2024

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Electroactive organic electrode materials exhibit remarkable potential in aqueous zinc ion batteries (AZIBs) due to their abundant availability, customizable structures, sustainability, and high reversibility. However, the research on AZIBs has predominantly concentrated on unraveling the storage mechanism of zinc cations, often neglecting the significance of anions in this regard. Herein, bipolar poly(thionine) is synthesized by a simple and efficient polymerization reaction, and the kinetics of different anions are investigated using poly(thionine) as the cathode of AZIBs. Notably, poly(thionine) is a bipolar organic polymer electrode material and exhibits enhanced stability in aqueous solutions compared to thionine monomers. Kinetic analysis reveals that ClO4− exhibits the fastest kinetics among SO42−, Cl−, and OTF−, demonstrating excellent rate performance (109 mAh g−1 @ 0.5 A g−1 and 92 mAh g−1 @ 20 A g−1). Mechanism studies reveal that the poly(thionine) cathode facilitates the co‐storage of both anions and cations in Zn(ClO4)2. Furthermore, the lower electrostatic potential of ClO4− influences the strength of hydrogen bonding with water molecules, thereby enhancing the overall kinetics in aqueous electrolytes. This work provides an effective strategy for synthesizing high‐quality organic materials and offers new insights into the kinetic behavior of anions in AZIBs.

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Amorphous metal–organic frameworks: Pioneering frontiers in cancer diagnostics and therapeutics

Zhao,

Zhang,

Luo

et al. 2024

Chemical Engineering Journal

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A two-enzyme system in an amorphous metal–organic framework for the synthesis of d-phenyllactic acid

Abstract: An amorphous biocatalyst (LDH/GDH–aZIF-90) for the synthesis of d-phenyllactic acid was constructed for the first time, and it achieved coenzyme recycling and demonstrated excellent stability and recyclability.

Cited by 3 publications

References 43 publications

Strong coordination interaction in amorphous Sn-Ti-ethylene glycol compound for stable Li-ion storage

Strong coordination interaction in amorphous Sn-Ti-ethylene glycol compound for stable Li-ion storage

Insight into Anionic Discrepancies in Bipolar Poly(Thionine) Organic Cathodes for Aqueous Zinc Ion Batteries

Amorphous metal–organic frameworks: Pioneering frontiers in cancer diagnostics and therapeutics

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