A three-dimensional supramolecular framework of silver(I), 2-phenylquinoline-4-carboxylate and 4,4′-bipyridine

Guo, Jiansheng; Guo, Bing-Xin; Wu, Jiangyu; Yan, Guoping

doi:10.1107/s010827011301559x

Cited by 3 publications

(1 citation statement)

References 20 publications

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“…Huang et al (2013) reported a silver(I) CP formed with benzene-1,3,5-tricarboxylic acid and pyrazine. In addition, Guo's group successfully obtained a threedimensional silver(I) CP based on 2-phenylquinoline-4carboxylate and 4,4 0 -bipyridine (Guo et al, 2013). However, less attention has hitherto been focused on flexible ligands, especially on asymmetric flexible bridges (Wei et al, 2009).…”

Section: Introductionmentioning

confidence: 99%

A one-dimensional silver(I) coordination polymer based on an asymmetric flexibleN-donor carboxylate ligand:catena-poly[(μ₃-4-{[(1-phenyl-1H-tetrazol-5-yl)sulfanyl]methyl}benzoato-κ³O:O′:N⁴)silver(I)]

Zhang¹,

Zhang²,

Wang³

et al. 2014

Acta Crystallogr C

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The title compound, [Ag(C15H11N4O2S)]n, was synthesized by the reaction of 4-{[(1-phenyl-1H-tetrazol-5-yl)sulfanyl]methyl}benzoic acid (Hptmba) with silver nitrate and triethylamine at room temperature. The asymmetric unit contains one crystallographically independent Ag(I) cation and one ptmba(-) ligand. Each Ag(I) cation is tricoordinated by two carboxylate O atoms and one tetrazole N atom from three different ptmba(-) ligands, displaying a distorted T-shaped geometry. Three Ag(I) cations are linked by tris-monodentate bridging ptmba(-) ligands to form a one-dimensional double chain along the c axis, which is further consolidated by an intrachain π-π contact with an offset face-to-face distance of 4.176 (3) Å between the centroids of two adjacent aromatic rings in neighbouring benzoate groups. The one-dimensional chains are linked into a three-dimensional supramolecular framework by additional π-π interchain interactions, viz. of 3.753 (3) Å between two phenyl substituents of the tetrazole rings and of 4.326 (2) Å between a benzoate ring and a tetrazole ring. Thermogravimetric analysis and the fluorescence spectrum of the title compound reveal its good thermal stability and a strong green luminescence at room temperature.

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Section: Introductionmentioning

confidence: 99%

A one-dimensional silver(I) coordination polymer based on an asymmetric flexibleN-donor carboxylate ligand:catena-poly[(μ₃-4-{[(1-phenyl-1H-tetrazol-5-yl)sulfanyl]methyl}benzoato-κ³O:O′:N⁴)silver(I)]

Zhang¹,

Zhang²,

Wang³

et al. 2014

Acta Crystallogr C

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Synthesis, characterization and the fluorescent enhancement mechanism of bonded poly(Eu(TTA)2(phen)MAA-co-VA) nanofibers by electrospinning

et al. 2020

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Ligand effects on the structural dimensionality and antibacterial activities of silver-based coordination polymers

Sun

et al. 2014

Dalton Trans.

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Four Ag-based coordination polymers [Ag(Bim)] (1), [Ag2(NIPH)(HBim)] (2), [Ag6(4-NPTA)(Bim)4] (3) and [Ag2(3-NPTA)(bipy)0.5(H2O)] (4) (HBim = 1H-benzimidazole, bipy = 4,4'-bipyridyl, H2NIPH = 5-nitroisophthalic acid, H2NPTA = 3-/4-nitrophthalic acid) have been synthesized by hydrothermal reaction of Ag(i) salts with N-/O-donor ligands. Single-crystal X-ray diffraction indicated that these coordination polymers constructed from mononuclear or polynuclear silver building blocks exhibit three typical structure features from 1-D to 3-D frameworks. These compounds favour a slow release of Ag(+) ions leading to excellent and long-term antimicrobial activities, which is distinguished by their different topological structures, towards both Gram-negative bacteria, Escherichia coli (E. coli) and Gram-positive bacteria, Staphylococcus aureus (S. aureus). In addition, these compounds show good thermal stability and light stability under UV-vis and visible light, which are important characteristics for their further application in antibacterial agents.

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A three-dimensional supramolecular framework of silver(I), 2-phenylquinoline-4-carboxylate and 4,4′-bipyridine

Cited by 3 publications

References 20 publications

A one-dimensional silver(I) coordination polymer based on an asymmetric flexibleN-donor carboxylate ligand:catena-poly[(μ₃-4-{[(1-phenyl-1H-tetrazol-5-yl)sulfanyl]methyl}benzoato-κ³O:O′:N⁴)silver(I)]

A one-dimensional silver(I) coordination polymer based on an asymmetric flexibleN-donor carboxylate ligand:catena-poly[(μ₃-4-{[(1-phenyl-1H-tetrazol-5-yl)sulfanyl]methyl}benzoato-κ³O:O′:N⁴)silver(I)]

Synthesis, characterization and the fluorescent enhancement mechanism of bonded poly(Eu(TTA)2(phen)MAA-co-VA) nanofibers by electrospinning

Ligand effects on the structural dimensionality and antibacterial activities of silver-based coordination polymers

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A three-dimensional supramolecular framework of silver(I), 2-phenylquinoline-4-carboxylate and 4,4′-bipyridine

Cited by 3 publications

References 20 publications

A one-dimensional silver(I) coordination polymer based on an asymmetric flexibleN-donor carboxylate ligand:catena-poly[(μ3-4-{[(1-phenyl-1H-tetrazol-5-yl)sulfanyl]methyl}benzoato-κ3O:O′:N4)silver(I)]

A one-dimensional silver(I) coordination polymer based on an asymmetric flexibleN-donor carboxylate ligand:catena-poly[(μ3-4-{[(1-phenyl-1H-tetrazol-5-yl)sulfanyl]methyl}benzoato-κ3O:O′:N4)silver(I)]

Synthesis, characterization and the fluorescent enhancement mechanism of bonded poly(Eu(TTA)2(phen)MAA-co-VA) nanofibers by electrospinning

Ligand effects on the structural dimensionality and antibacterial activities of silver-based coordination polymers

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Product

Resources

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A one-dimensional silver(I) coordination polymer based on an asymmetric flexibleN-donor carboxylate ligand:catena-poly[(μ₃-4-{[(1-phenyl-1H-tetrazol-5-yl)sulfanyl]methyl}benzoato-κ³O:O′:N⁴)silver(I)]

A one-dimensional silver(I) coordination polymer based on an asymmetric flexibleN-donor carboxylate ligand:catena-poly[(μ₃-4-{[(1-phenyl-1H-tetrazol-5-yl)sulfanyl]methyl}benzoato-κ³O:O′:N⁴)silver(I)]