Retrieval of parameters in a non-Fourier conduction and radiation heat transfer problem is reported. The direct problem is formulated using the lattice Boltzmann method (LBM) and the finite-volume method (FVM). The divergence of radiative heat flux is computed using the FVM, and the LBM formulation is employed to obtain the temperature field. In the inverse method, this temperature field is taken as exact. Simultaneous estimation of parameters, namely, the extinction coefficient and the conduction-radiation parameter, is done by minimizing the objective function. The genetic algorithm (GA) is used for this purpose. The accuracies of the estimated parameters are studied for the effects of measurement errors and genetic parameters such as the crossover and mutation probabilities, the population size, and the number of generations. The LBM-FVM in combination with GA has been found to provide a correct estimate of parameters.