Objectives:To evaluate the polymerization efficiency of bulk fill resin-based composites (RBCs) and how their composition, temperature and post-irradiation polymerization influence the results. Methods and Materials: Eight bulk fill RBCs were investigated. Five specimens for each material were prepared for Vickers hardness measurements. The measurements were performed in three depths from the top of the surface of the specimens (0, 2 or 4 mm) immediately and 24 h after polymerization and for the highly viscous bulk fill RBCs after preheating at 54 o C. Statistical analysis was performed using one-way ANOVA and Tukey post hoc tests at a=0.05. Results: As the depth increases microhardness values reduce. The Vickers hardness measurements 24 h after photo-polymerization revealed higher values compared to those obtained immediately after photo-polymerization (p<0.05). There was an increase in microhardness of the RBC materials when preheated at 54 o C in comparison with the room temperature specimens (p<0.05).Conclusions: Polymerization efficiency of bulk fill RBCs is affected by their composition and increases with temperature and post-irradiation polymerization.