Developing stretchable/wearable strain sensors in different
application
scenarios is a global demand for creating a smart society and promoting
healthcare, whereas existing hydrogel-based strain sensors suffer
from limited sensitivity, low conductance and hydrophilicity, making
them difficult to operate underwater. In this work, a highly sensitive,
stretchable, and hydrophobic strain sensor is fabricated by coating
a layer of reduced graphene oxide (rGO) sheets on the surface of organohydrogel.
Furthermore, a facile solvent-replacement approach is utilized to
enhance the anti-freezing and anti-drying abilities of hydrogel simultaneously
by incorporating propanediol in the solvent. Consequently, the obtained
rGO-organohydrogel composite strain sensor features a high gauge factor
of 140, a low detection limit of 0.1% strain, a wide detection range
(0–400% strain), a fast response time of 190 ms, excellent
stability and repeatability, and high hydrophobicity (contact angle
of 122°), making it applicable for a wide range of application
scenarios, such as the real-time and continuous monitoring of various
human motions in extremely cold (−60 °C), dry, and underwater
environments. The sensitivity of an rGO-modified organohydrogel strain
sensor is more than 30 times higher than that of its unmodified counterpart,
which is attributed to the cracking and tunneling effects introduced
by the highly conductive rGO surface layer upon stretching.