Absfruct-In this paper, we demonstrate the superior diffusion barrier properties of NO-nitrided SiOn in suppressing boron penetration for p+-polysilicon gated MOS devices. Boron penetration effects have been studied in terms of flatband voltage shift, decrease in inversion capacitance (due to polysilicon depletion effect), impact on interface state density, and chargeto-breakdown. Results show that NO-nitrided SiOz, as compared to conventional thermal SiOz, exhibit much higher resistance to boron penetration, and therefore, are very attractive for surface channel PMOS technology.N deep-submicrometer CMOS technology, p+-polysilicon I as the gate material for p-channel MOSFET is required to improve short-channel behavior [ 11, [2]. Unfortunately, boron diffusion from heavily doped p+-polysilicon through the thin gate oxide and into the underlying channel region can cause undesirable degradation of device operation, including instability in threshold voltage control, increase in charge trapping rate, decrease in low-field mobility [3], [4], and reduced current drivability due to polysilicon depletion in p-MOSFET's [5]. Previous studies have shown that "3-nitrided oxides and NZO-based oxides can suppress boron penetration [6]-[ IO]. However, "3-nitrided oxides suffer from hydrogen-related electron trapping problems [ 111 and NZO-based oxides require a much higher thermal budget for sufficient nitrogen concentration ([NI) to effectively suppress boron penetration 171. In this letter, we report the use of rapid thermal NO-nitrided Si02 as an alternate oxynitride with enhanced boron diffusion barrier properties while maintaining a low thermal budget and H-free nature of the processing ambient. The applicability of RTP NO-nitrided Si02 as gate dielectric in n+-poly gated MOSFET's has been recently demonstrated [12]. In this study, we examine the effects of boron penetration on flatband voltage (Vh), inversion capacitance (due to polysilicon depletion effect), interface state density (Dit), and charge-to-breakdown ( QBD) characteristics for p+-poly gated MOS devices. were fabricated on 10-15 0-cm, n-typeSi ( 100) substrates. All oxidation and nitridation processes were performed in a rapid thermal processing (RTP) system at 1 atm. Thermal oxides grown at 1050°C in pure 0 2 were used as control samples. Some samples then received in situ nitridation at 1000°C for 10 or 100 s in pure NO ambient. All samples finally received an in situ N2 anneal at 1050°Cfor 20 s. Undoped polysilicon with a thickness of 4000 8, was deposited by LPCVD at 625°C followed by BFz implants at 20 KeV with a dose of 5.5 x 1015 cm-'. Before the patterning of polysilicon, furnace N2 annealing for 30 min. at different temperatures (850, 900, and 950°C) was used to activate and redistributed the implanted boron. The final oxide thicknesses (measured by C-V) were -55 and -57A for control and the two NO-nitrided oxides, respectively.SIMS measurement (Fig. 1) reveals that the peak nitrogen concentration at the SiOz/Si interface for 1000°C/lOO s and 1000°C/...