2020
DOI: 10.2478/msp-2020-0057
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A study of nickel and cobalt silicides formed in the Ni/Co/Si(1 0 0) system by thermal annealing

Abstract: In this work, the Ni/Co/Si system was annealed at temperatures ranging from 300 °C to 800 °C. The samples were characterized by means of X-ray diffraction (XRD), Raman spectroscopy, Rutherford backscattering spectroscopy (RBS), atomic force microscopy (AFM) and sheet resistance measurement. The XRD and Raman spectroscopy results showed that the formation of nickel and cobalt silicides (CoSi, Co2Si, Ni2Si, NiSi, NiSi2, CoSi2) is an annealing temperature dependent diffusion process. The diffusion phenomenon was … Show more

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Cited by 2 publications
(2 citation statements)
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“… 30 For sample 3.8R, these two broad peaks get much weaker, indicating the beginning of the recrystallization of the amorphous Si capping layer. For sample 4.0R, one peak at around 150 cm –1 and another peak at around 200 cm –1 appear, corresponding to Co 2 Si and CoSi, 31 respectively. It means that sample 4.0R contains two phases.…”
Section: Resultsmentioning
confidence: 98%
“… 30 For sample 3.8R, these two broad peaks get much weaker, indicating the beginning of the recrystallization of the amorphous Si capping layer. For sample 4.0R, one peak at around 150 cm –1 and another peak at around 200 cm –1 appear, corresponding to Co 2 Si and CoSi, 31 respectively. It means that sample 4.0R contains two phases.…”
Section: Resultsmentioning
confidence: 98%
“…One of the crucial problems during the production of austenitic steel forgings is increased adhesion of the charge material-chromium-nickel steel with the nickel content of 24-35% and chromium content of 14-20%-to the tool substrate (in the case of the first operation-extrusion-to the die, and the second operation-to the punch) made of tool steel [1]. This results from the difficulty in shaping steel with a high content of nickel and a poor selection of the process parameters [16,17]. As a result of high pressures at high temperatures as well as a long path of friction, in the case of the punch used in the second forging operation, we observe wear [18] (mainly abrasive wear as well as material tempering causing plastic deformation) of the so-called "calotte" on the head surface in the tool axis.…”
Section: Introductionmentioning
confidence: 99%