A State-of-the-Art Review on the Technological Advancements for the Sustainable Management of Plastic Waste in Consort with the Generation of Energy and Value-Added Chemicals
Abstract:Plastic waste poses a serious threat to the environment and it has been increasing at an alarming rate. In 2022, global plastic waste generation was reported to be around 380 million tonnes as compared to 353 million tonnes in 2019. Production of liquid fuel from plastic waste is regarded as a viable method for disposing of the plastic and utilizing its energy. Currently, a wide range of technologies have been explored for turning plastic waste into fuel, including the conventional pyrolysis, incineration, gas… Show more
“…The I D /I G ratios for torre ed rice straw at different temperatures are shown in Table 4. The I D /I G ratio decreased with increasing torrefaction temperature and time, which indicates that the carbon structures became more ordered and, conversely, could possess a lower graphitization degree at higher temperatures, which is in agreement with the literature results [40][41][42][43]45].…”
Section: Raman Spectra Of Torre Ed Rice Strawsupporting
The surplus biomass residue generated from biomass harvesting has enough potential for generating bioenergy and is a promising energy source for future use. Biomass possesses a high moisture content and low calorific value and therefore needs improvement to convert it into solid biofuel. In the present study, torrefaction of lignocellulosic biomass (rice straw) was carried out to enhance its physicochemical characteristics for producing high-grade biofuels and chemicals. For three sets of temperatures (200, 250, and 300°C) and residence times (30 minutes, 45 minutes, and 60 minutes), experiments were conducted in a batch reactor at a heating rate of 10°C.min− 1 in an inert environment. The torrefied products obtained were analyzed using various analytical techniques, such as proximate and ultimate analysis, calorific value measurement, and FTIR analysis. The results revealed that torrefaction at a mild temperature of 200°C and 30 minutes of residence time resulted in a maximum mass yield of 87% and an energy yield of 97%, which subsequently decreased at higher temperatures. The calorific value increased with increasing torrefaction temperature, with a maximum value of 19.50 MJ.kg− 1 occurring at 300°C and 60 minutes of residence time. Since H2O, CO, and CO2 are released upon torrefaction, a significant decrease in the number of hydroxyl groups was observed in the FTIR spectra. Despite the high calorific value at 300°C, 250°C and 30 minutes of residence time are the optimum torrefaction conditions for rice straw due to the significant mass and energy yield and the significant presence of amorphous carbon, as confirmed by Raman spectroscopy. This study will improve the physicochemical properties of rice straw for the production of high-value fuels, chemicals, and other high-strength materials.
“…The I D /I G ratios for torre ed rice straw at different temperatures are shown in Table 4. The I D /I G ratio decreased with increasing torrefaction temperature and time, which indicates that the carbon structures became more ordered and, conversely, could possess a lower graphitization degree at higher temperatures, which is in agreement with the literature results [40][41][42][43]45].…”
Section: Raman Spectra Of Torre Ed Rice Strawsupporting
The surplus biomass residue generated from biomass harvesting has enough potential for generating bioenergy and is a promising energy source for future use. Biomass possesses a high moisture content and low calorific value and therefore needs improvement to convert it into solid biofuel. In the present study, torrefaction of lignocellulosic biomass (rice straw) was carried out to enhance its physicochemical characteristics for producing high-grade biofuels and chemicals. For three sets of temperatures (200, 250, and 300°C) and residence times (30 minutes, 45 minutes, and 60 minutes), experiments were conducted in a batch reactor at a heating rate of 10°C.min− 1 in an inert environment. The torrefied products obtained were analyzed using various analytical techniques, such as proximate and ultimate analysis, calorific value measurement, and FTIR analysis. The results revealed that torrefaction at a mild temperature of 200°C and 30 minutes of residence time resulted in a maximum mass yield of 87% and an energy yield of 97%, which subsequently decreased at higher temperatures. The calorific value increased with increasing torrefaction temperature, with a maximum value of 19.50 MJ.kg− 1 occurring at 300°C and 60 minutes of residence time. Since H2O, CO, and CO2 are released upon torrefaction, a significant decrease in the number of hydroxyl groups was observed in the FTIR spectra. Despite the high calorific value at 300°C, 250°C and 30 minutes of residence time are the optimum torrefaction conditions for rice straw due to the significant mass and energy yield and the significant presence of amorphous carbon, as confirmed by Raman spectroscopy. This study will improve the physicochemical properties of rice straw for the production of high-value fuels, chemicals, and other high-strength materials.
“…Indirect oxidation employing potent oxidizing intermediates predominates in the conversion of plastics, whereas direct oxidation corresponds to the electrophilic assault on a polymer by OH created by water discharge on the anode surface. 106 For example, Fig. 14a shows electrocatalyst reforming process of for direct oxidation polyethylene terephthalate (PET) by using palladium modified nickel foam (Pd/NF) anode and pure NF cathode.…”
Hydrogen fuel sources will undoubtedly become the center of the future fuel revolution to replace fossil fuels. As a result, there is an increased demand for research into methods and solutions for producing clean hydrogen.
“…In fluidised bed gasifiers, silica or alumina, which have high specific heat capacities and thermal stability, is used as bed materials. 20 In some cases, catalysts may be added with the bed material. 21 The gasifying agent fluidises the bed and the biomass, leading to enhanced heat transfer, increased reaction rates, short residence times and higher conversion efficiencies compared to fixed bed gasifiers.…”
Conventional biomass gasification involves a complex set of chemical reactions leading to the production of a product gas mainly composed on carbon monoxide, hydrogen, carbon dioxide and methane.
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