A Simple Synthesis of Phospholes

Märkl, Gottfried; Potthast, R.

doi:10.1002/anie.196700861

Cited by 56 publications

(30 citation statements)

References 7 publications

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“…Compounds 1 and 2 have been prepared according to published procedures , . For the synthesis of phospholes 3 and 4 the procedure was slightly changed.…”

Section: Methodsmentioning

confidence: 99%

Tailoring Phospholes for Imprint of Fluorescent 3D Structures

et al. 2019

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PMMA based polymer blends have been infused with luminescent phospholes and have been structured via nanoimprint. While symmetrically substituted phospholes are prone to crystallization and phase separation, structural modification of the phosphole backbone in the αand -positions has been explored, which prevents these issues; a structural explanation for this is suggested. Best phase integrity has been [a]

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“…Compounds 1 and 2 have been prepared according to published procedures , . For the synthesis of phospholes 3 and 4 the procedure was slightly changed.…”

Section: Methodsmentioning

confidence: 99%

Tailoring Phospholes for Imprint of Fluorescent 3D Structures

et al. 2019

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“…From 1,3-Diynes and Primary Phosphines. In the very early days of phosphole chemistry, Märkl and Potthast [27] developed a method for construction of the phosphole ring by cycloaddition of diynes and primary phosphines. The method continues to find occasional use, and now has been used to construct a phosphole (45, 5.60) with the optically active (-)-menthyl group in the 2,5-positions [28].…”

Section: Thfmentioning

confidence: 99%

The Continuing Development of the Chemistry of Phospholes

Quin¹

2006

COC

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The last five years have seen many advances in the chemistry of phospholes. Motivating much of the work has been the potential for discovering valuable applications of phospholes, especially as ligands in metal coordination compounds designed for use as homogeneous catalysts, and in the field of electro-optical substances. This review covers the research in the synthesis, properties and applications of phospholes that has been published since the last comprehensive review by the author in 1999. While prepared for the specialist, the review is designed to introduce some of the aspects of phosphole chemistry to the general reader.

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“…Similar reactions are entered into (31,32) by pyrroles and arsoles. Since phospholes substituted only on the phosphorus atom are now known (9,10,18), this may prove to be a possible route to the as yet unknown parent phosphole (I).…”

Section: Imentioning

confidence: 99%

The chemistry of phosphole derivatives

Hughes

Srivanavit

1970

Journal of Heterocyclic Chem

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Synthetic approaches to, and the chemistry of, phospholes, benzophospholes and dibenzophospholes are reviewed and particular attention is paid to the possible aromatic character of the phosphole ring. Systems containing the 2H‐ and 3H‐phosph(V)ole nucleus are surveyed as are phosphole derivatives containing pentacovalent and six‐coordinate phosphorus. Stereochemical considerations in the more complex phosphole derivatives are discussed.

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A Simple Synthesis of Phospholes

Cited by 56 publications

References 7 publications

Tailoring Phospholes for Imprint of Fluorescent 3D Structures

Tailoring Phospholes for Imprint of Fluorescent 3D Structures

The Continuing Development of the Chemistry of Phospholes

The chemistry of phosphole derivatives

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