Bismuth selenide, Bi 2 Se 3 , nanoparticles were synthesized by a new precursor complex, [bis(salicylate)bismuth(II)]; [Bi 2 (Hsal) 3 ], via a sonochemical method in an aqueous solution. The average diameter of the Bi 2 Se 3 nanoparticles was 25 nm. The efficiency of the Bi 2 Se 3 nanoparticles as a photocatalyst for the decolorization of rhodamine-B and methylene blue using ultraviolet light irradiation has been evaluated. Furthermore, a preliminary study on the possibility of developing a solar cell having the FTO/TiO 2 /Bi 2 Se 3 /Pt-FTO structure was also investigated to produce an inexpensive solar cell by Bi 2 Se 3 nanoparticles. Products were characterized by X-ray diffraction, scanning electron microscopy, transmission electron microscopy, photoluminescence, and EDX analysis.