Ahstraet:The y-radiation produced by thermal neutron capture in enriched "'Ti and @Ti targets has been investigated.In the analysis 57 excited states of 48Ti and 31 of soTi have been identified. The Q-value of the 47Ti(n, y) reaction, 11 626.66(4) keV, is in agreement with previous data. The present value for 49Ti, 10 939.20(4) keV, differs by five standard deviations from a previous result.The nature of the neutron-capture mechanism has been investigated by comparing the present results with those from previous (d, p) work. It appears that in 47Ti capture proceeds through a doorway state and that the potential capture formalism is valid for 49Ti. Yet the @Ti cross section for transitions to p-states is predicted low by a factor of 4. The Fermi gas model gives a good representation of the nuclear level density in both nuclei. The combination of nuclear orientation measurements and circular polarization measurements has yielded the unambiguous determination of the spins of one 48Ti state and of five soTi states. Further spin and parity determinations for six 48Ti and for five "Ti states have been obtained from the analysis of the identified branches together with the results of previous experiments.Shell-model calculations, which yielded excitation energies, branching ratios, lifetimes and (d, p) spectroscopic factors, give a good representation of the experimental data for the low-lying states in both nuclei. NUCLEAR REACTIONS 47Ti(n, y), (polarized n, i), @Ti(n, y), (polarized n, +), E = E thermal; measured E,, I,(E,, 0), y-CP; deduced Q-values, 48Ti deduced levels, y-branching, J, rr, soTi deduced levels, y-branching, J, n. Enriched, polarized, unpolarized targets.