“…In 2014, Lam reported the enantioselective rhodium-catalyzed addition of arylboronic acids 116 to alkenyl azaarenes 115 using a 2,4,6-triisopropylanilide-containing chiral diene ligand XIII (Scheme 29). [23] This report represents an improvement of the previous reaction conducted with a compound containing (2S)-(2,5-dimethylpyrrol-1-yl)-(1S)-cyclohexylamine as the amino group of the ligand. [24] The azaarene group spans from monocyclic oxazole, 1,2,4oxadiazole, 1,3,4-oxadiazole, pyrimidine, pyrazine, triazine, to bicyclic compound as quinoline, quinazoline, benzoxazole, and benzothiazole.…”