2019
DOI: 10.1007/s10973-019-08244-2
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A review on the application of differential scanning calorimetry (DSC) to petroleum products

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Cited by 32 publications
(9 citation statements)
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“…Water is present in almost all steps of crude oil production including exploitation, upgrading, transportation and processing [95] (see also Introduction). Therefore, it is important to evaluate the effect of water on thermodynamic (density) and transport (viscosity) properties oil-water emulsions.…”
Section: Water-in-oil Emulsion Preparation and Stabilitymentioning
confidence: 99%
“…Water is present in almost all steps of crude oil production including exploitation, upgrading, transportation and processing [95] (see also Introduction). Therefore, it is important to evaluate the effect of water on thermodynamic (density) and transport (viscosity) properties oil-water emulsions.…”
Section: Water-in-oil Emulsion Preparation and Stabilitymentioning
confidence: 99%
“…It should be mentioned that some authors suggest that the solidus temperature should be used instead of the liquidus temperature [63]. Nonetheless, γ (γ = T x /(T g + T l ) parameter [64], and a reduced glass transition temperature (T rg= T g /T l ) are included in a lot of articles. The solidus temperature is the temperature below which there are only solid phases in equilibrium.…”
Section: Melting Temperature and Liquidus Temperaturementioning
confidence: 99%
“…To explore the impact of confinement effects and to inspect the influence of the APTES modification of the pore surface on the structure and dynamics of ethylene glycol, a combination of differential scanning calorimetry (DSC) and variable-temperature 2 H solid-state NMR ( 2 H ssNMR) is suitable, as recently demonstrated for 1-octanol in porous silica by some of the authors . DSC provides information on physical processes such as melting, crystallization, or glass transitions of ethylene glycol in a confined environment. Solid-state NMR provides information on the onset of rovibrational motions, which may occur at temperatures different from the macroscopic phase transitions. , Insights into dynamics are accessible by extracting NMR parameters encoded in the line shape of the spectra recorded at different temperatures. For example, the use of quadrupolar nuclei such as deuterium allows for the analysis of intramolecular motions in deuterated molecules via changes in the 2 H ssNMR line shapes. Thus, the combination of DSC and 2 H ssNMR allows for studying the behavior of the ethylene glycol inside the pores of silica materials and inspecting the impact of the APTES functionalization on the structure and dynamics of the ethylene glycol in confinement.…”
Section: Introductionmentioning
confidence: 99%