Abstract:In recent years, metal-organic frameworks (MOFs) have been widely used in various fields, including electrochemical energy storage and conversion because of their excellent properties, such as high specific surface area,...
“…[264][265][266][267][268] The conductive carbon (eg, graphene, carbon nanofibers/nanotubes) have shown a great promise as the 3D host materials in recent alkali-metal batteries. 260,[269][270][271][272][273][274][275][276][277][278][279][280] Li et al 270 reported 3D porous carbon network promoted a uniform distribution of current density resulting in carbon network mitigating the formation of Li dendrite effectively. Wu et al 275 suggested rGO aerogel as stable host for NIB, which reveals excellent cycling stability at a high current density of 5 mA cm À2 .…”
Section: Carbon Host For Metal-free Anodementioning
confidence: 99%
“…Analogous to LIB and NIB systems, the carbon materials for the host have been applied to KIB. 260,[277][278][279][280] Qin et al 277 fabricated an anode containing metallic K infused on an aligned carbon nanotube membrane (ACM); this structure has better cycling performance due to a good wettability to potassium. A strong capillary force obtained from the ACM host offers adequate K nucleation sites for confining the deposited K and smooth charge transfer between electrode and electrolyte during cycling.…”
Section: Carbon Host For Metal-free Anodementioning
Li-ion batteries (LIBs) are being used extensively in a wide range of applications owing to the facile preparation technology as well as a high energy density, which exceeds those of other commercial batteries. However, LIBs alone cannot satisfy the burgeoning energy demand due to Li-resource constraints.Recently, K-ion batteries (KIBs) have garnered the interest of the scientific community as promising alternatives for LIBs due to the abundance of K resources, the affordability of K, and its superior electrochemical properties. However, the development of KIBs is hindered by the slow development of appropriate anode materials that can accommodate the repeated intercalation/ deintercalation of large K ions without sustaining significant structural damage. Thus, the development of appropriate anode materials is crucial for the realization of practically viable KIBs. Carbon nanomaterials are promising anode materials due to their remarkable potassiation/depotassiation ability, structural stability, and structural evolution from zero to three dimensions. It is anticipated that an evaluation of the recent advances in carbon and their composites anode materials for KIBs can facilitate the development of practically viable KIBs. This review comprehensively discusses recent developments in carbonaceous and their composites as anode materials for KIBs and provides a prospective for the next research step.
“…[264][265][266][267][268] The conductive carbon (eg, graphene, carbon nanofibers/nanotubes) have shown a great promise as the 3D host materials in recent alkali-metal batteries. 260,[269][270][271][272][273][274][275][276][277][278][279][280] Li et al 270 reported 3D porous carbon network promoted a uniform distribution of current density resulting in carbon network mitigating the formation of Li dendrite effectively. Wu et al 275 suggested rGO aerogel as stable host for NIB, which reveals excellent cycling stability at a high current density of 5 mA cm À2 .…”
Section: Carbon Host For Metal-free Anodementioning
confidence: 99%
“…Analogous to LIB and NIB systems, the carbon materials for the host have been applied to KIB. 260,[277][278][279][280] Qin et al 277 fabricated an anode containing metallic K infused on an aligned carbon nanotube membrane (ACM); this structure has better cycling performance due to a good wettability to potassium. A strong capillary force obtained from the ACM host offers adequate K nucleation sites for confining the deposited K and smooth charge transfer between electrode and electrolyte during cycling.…”
Section: Carbon Host For Metal-free Anodementioning
Li-ion batteries (LIBs) are being used extensively in a wide range of applications owing to the facile preparation technology as well as a high energy density, which exceeds those of other commercial batteries. However, LIBs alone cannot satisfy the burgeoning energy demand due to Li-resource constraints.Recently, K-ion batteries (KIBs) have garnered the interest of the scientific community as promising alternatives for LIBs due to the abundance of K resources, the affordability of K, and its superior electrochemical properties. However, the development of KIBs is hindered by the slow development of appropriate anode materials that can accommodate the repeated intercalation/ deintercalation of large K ions without sustaining significant structural damage. Thus, the development of appropriate anode materials is crucial for the realization of practically viable KIBs. Carbon nanomaterials are promising anode materials due to their remarkable potassiation/depotassiation ability, structural stability, and structural evolution from zero to three dimensions. It is anticipated that an evaluation of the recent advances in carbon and their composites anode materials for KIBs can facilitate the development of practically viable KIBs. This review comprehensively discusses recent developments in carbonaceous and their composites as anode materials for KIBs and provides a prospective for the next research step.
“…[1][2][3] KIBs show several competitive advantages for future energy storage including highly abundant electrode materials, 4 even distribution of potassium sources across the globe, 5 fast ion diffusion in organic electrolytes, 6 comparable voltage capabilities to LIBs, 7,8 and compatibility with low-weight Al current collectors. 7,9 On the path toward high-voltage and long cycle life KIBs, substantial research efforts are focused on developing improved electrode materials 4,[10][11][12][13][14][15] and optimization of the electrolyte. 8,9,16 While signicant progress has been made, more effort is still needed to maintain KIBs as a competitive alternative to LIBs.…”
Graphite is a promising negative electrode material for emerging potassium ion batteries (KIBs), offering a good capacity and a low-potential discharge plateau. To date, achieving long cycle life KIBs with...
“…Besides, the strategy is scalable and is anticipated to be applied to other MOF-based materials. 77 Additionally, the diverse in situ characteristics in the catalytic course of oxygen evolution reaction (OER), 78,79 HER, [80][81][82] and oxygen reduction reaction (ORR), 75,[83][84][85] as well as other reactions, the excellent performance in terms of electrochemical energy storage, and the application of SCs, 86 sodium-ion batteries (SIBs), [87][88][89][90] lithium-ion batteries (LIBs), [91][92][93][94][95] and other batteries [96][97][98] have been summarized and highlighted, which is expected to be valuable for comprehending the current advances made in MOF-derived phosphides and their utilization in various fields.…”
Because of features, such as adjustable structures, high porosity, and high crystallinity, metal–organic frameworks (MOFs) deservedly have received considerable attention. Nevertheless, there is still room for improvements in the electrical conductivity and chemical stability of some MOFs, because of which they cannot be utilized as electrode materials. Fortunately, MOF derivatives have received widespread attention in recent years, especially phosphide materials, which are widely used in practical applications because of their outstanding conductivity, excellent specific surface area, and standout charge mobility. In this review, the latest developments of MOF‐derived phosphides in electrocatalysis related to energy, including the excellent performance in terms of electrochemical energy storage and ingenious strategies, and diversified synthetic approaches have been emphasized and summarized. Additionally, the arduous task and feasible proposals of MOF‐derived phosphides are also discussed.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.