In this study, a phase-switching process is introduced
to a PM6:Y6-based
active layer to implement a uniform surface with preferred Y6 acceptor-domain
positioning and to minimize solution loss owing to the use of medium
molds. By designing the process to fit the surface properties of a
small-molecule Y6 acceptor-based bulk heterojunction, a sustainable
and highly reproducible phase-switched active layer that can be formed
at the desired location without wasting materials is successfully
formed over an area of 2.25 cm2. It improved charge transport
ability and suppressed surface defects owing to a molecular orientation
favorable for efficient charge separation and transport. Furthermore,
adding chloronaphthalene induced the domain growth of Y6 acceptors
with dense molecular packing, which enhanced the effects of the phase-switching
process. Uniformly distributed performance in the phase-switched active
layer via the phase-switching process was demonstrated in fabricated
large active-area devices. Furthermore, the process was utilized in
a PM6:Y6-based self-powered photodetector, which improved detectivity
owing to the suppression of the dark current density. Therefore, the
phase-switching process is an important technology for forming high-quality
thin films composed of small-molecule acceptors for efficient self-powered
photodetector and photovoltaic applications.