A preliminary investigation of the crystal and molecular structure of α-<scp>D</scp>-glucose monohydrate

Killean, R. C. G.; Ferrier, W. G.; Young, Douglas W.

doi:10.1107/s0365110x62002352

Cited by 34 publications

(5 citation statements)

References 0 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…Like in H 2 O ices, the aggregation of glucose molecules in crystals is governed mainly by OH/O hydrogen bonds. It was rst shown for the a-D-glucose monohydrate structure (monoclinic, space group P2 1 , Z 0 ¼ 2), determined in 1962 by Killean and Ferrier,8 in 1963 for b-D-glucose by Ferrier, 9 and in 1965 for a-D-glucose by Brown and Levy 10 (both orthorhombic, P2 1 2 1 2 1 , Z 0 ¼ 1). No solid-state phase transitions were reported for any of the glucose crystals so far.…”

Section: Introductionmentioning

confidence: 98%

Transformable H-bonds and conformation in compressed glucose

Patyk

Katrusiak

2015

Chem. Sci.

View full text Add to dashboard Cite

show abstract

Section: Introductionmentioning

confidence: 98%

Transformable H-bonds and conformation in compressed glucose

Patyk

Katrusiak

2015

Chem. Sci.

View full text Add to dashboard Cite

show abstract

“…The determination of the crystal structure of a-D-glucose monohydrate has been previously reported by Killean, Ferrier & Young (1962). Their study was based on visual estimation of Weissenberg photographs, and their model refined to an R of 0.17.…”

Section: Introductionmentioning

confidence: 99%

The crystal structure of α-D-glucose monohydrate

Hough¹,

Neidle²,

Rogers³

et al. 1973

Acta Crystallogr Sect B

View full text Add to dashboard Cite

& Boyd (1971). Further inspection of Fig. 2 suggests that the structure initially induced by the transition at 4800 kg cm -2 is not stable within the time scale of the X-ray exposure. For example the spacing of the (110) plane of the tetragonal structure at 4800 kg cm -2 still shows a little expansion with a further increase in pressure of 100 kg cm -2, as compared with Fig. 1, where steady reduction of the (110) spacing is seen above 5000 kg cm -2. In all these pressure regions, the (011) and (002) planes show steady decrease in spacing with increasing pressure and are more compressible than the (110) plane. Thus the crystal of adamantane after the transition is fairly anisotropic in the strains induced by hydrostatic pressures, being more compressible in the c direction than in the directions perpendicular to it. The strains are, however, isotropic before the transition, as shown by the cubic structure sustained under pressure (Fig. 1). The unit-cell dimension of the cubic structure just before the pressure transition is a= 9.20 A (at 4600 kg cm -2) and the calculated volumetric strain of the crystal at this stage is 6"9 %.It is worth while to note that at p, and 20°C, the crystal transition in adamantane arises in such a way that one of the original cubic axes shrinks 4.2 % and becomes parallel to the tetragonal c axis, while both of the other two axes expand 0.5% in the tetragonal [110] and [110] directions (numerical values were calculated at two pressures, 4600 and 5000 kg cm-2). The net effect is an abrapt volumetric contraction of 3-1%, which corresponds to abrupt molecular rearrangements toward denser packing.

show abstract

“…The author has undertaken a detailed examination of the crystal structure of E-D-glucose as a preliminary to a study of other more complex cellulose oligosaccharides. McDonald & Beevers (1950, 1952 determined the crystal structure of a-D-glucose and more recently Killean, Ferrier & Young (1962) determined the structure of a-D-glucose monohydrate. Both structures showed that the pyranose ring possessed the Sachse trans configuration.…”

mentioning

confidence: 99%

The crystal and molecular structure of β-D-glucose

Ferrier¹

1963

Acta Cryst

Self Cite

View full text Add to dashboard Cite

fl-D-Glucose (C6HlzO6) consists of a pyranose ring with substituents which are all equatorial. It crystallizes in the orthorhombic system with a = 9.29 ___ 0.04, b = 12-65 _ 0.02, c = 6.70 ___ 0.02 A. The space group is P212121 with 4 molecules in the cell. The crystal structure has been solved by a combination of a direct method and trial and error applied to two-dimensional data. The final refinement was obtained by an anisotropic least-squares analysis of approximately 850 observed three-dimensional structure factors. The three positional and six thermal parameters of all atoms except hydrogens have been determined.The pyranose ring is in the Sachse trans configuration and the ring oxygen bond angle is determined as 113 °. The detailed stereochemistry is compared with that of a-D-glucose and cellobiose.

show abstract

A preliminary investigation of the crystal and molecular structure of α-D-glucose monohydrate

Cited by 34 publications

References 0 publications

Transformable H-bonds and conformation in compressed glucose

Transformable H-bonds and conformation in compressed glucose

The crystal structure of α-D-glucose monohydrate

The crystal and molecular structure of β-D-glucose

Contact Info

Product

Resources

About