The photophysical characterization of two dyes used as
scintillators,
crystalline para-terphenyl and EJ-276, a plastic
heavily doped with 2,5-diphenyloxazole (DPO), was investigated with
steady-state absorption, time-resolved emission, and transient absorption
at room and cryogenic temperatures. Application of time-gated emission
spectroscopy allowed for the measurement of phosphorescence spectra
and their temporal dynamics. The photophysical properties of plastic-embedded
DPO are not substantially altered compared to those previously determined
for this dye in solvents. Notably, the amount of delayed fluorescence
is always greater than that of phosphorescence. However, our study
of crystalline para-terphenyl suggests that a second
phase called β (perhaps comprising more planar molecules) functions
as a triplet trap and decreases the amount of delayed fluorescence
relative to phosphorescence. While the “main form” of para-terphenyl dominates absorption, the emissive properties
(fluorescence, phosphorescence, and delayed fluorescence) are dominated
by the β-phase. Studies of the para-terphenyl
crystal performed with femtosecond time-resolved transient absorption
demonstrate that excitation from the main form of the para-terphenyl crystal is promptly transferred to the β-phase with
a time constant of roughly 300 ps. This work provides insight into
the photophysical properties of two scintillators utilized to differentiate
γ-ray- and neutron-induced signals.