Evaluation of the Photophysical Properties of Two Scintillators: Crystalline Para-terphenyl and Plastic-Embedded 2,5-Diphenyloxazole Dye (EJ-276) at Room and Cryogenic Temperatures

Abstract

The photophysical characterization of two dyes used as scintillators, crystalline para-terphenyl and EJ-276, a plastic heavily doped with 2,5-diphenyloxazole (DPO), was investigated with steady-state absorption, time-resolved emission, and transient absorption at room and cryogenic temperatures. Application of time-gated emission spectroscopy allowed for the measurement of phosphorescence spectra and their temporal dynamics. The photophysical properties of plastic-embedded DPO are not substantially altered compared to those previously determined for this dye in solvents. Notably, the amount of delayed fluorescence is always greater than that of phosphorescence. However, our study of crystalline para-terphenyl suggests that a second phase called β (perhaps comprising more planar molecules) functions as a triplet trap and decreases the amount of delayed fluorescence relative to phosphorescence. While the “main form” of para-terphenyl dominates absorption, the emissive properties (fluorescence, phosphorescence, and delayed fluorescence) are dominated by the β-phase. Studies of the para-terphenyl crystal performed with femtosecond time-resolved transient absorption demonstrate that excitation from the main form of the para-terphenyl crystal is promptly transferred to the β-phase with a time constant of roughly 300 ps. This work provides insight into the photophysical properties of two scintillators utilized to differentiate γ-ray- and neutron-induced signals.

Crystalline organic monoliths with bicontinuous porosity

“…As a triplet sensitizer, we chose Ir(ppy) 3, which has a suitable T 1 energy level ( T 1 = 2.48 eV) 42 for efficient triplet energy transfer to TP crystals ( T 1 = 2.15 eV). 43 …”

“…As a triplet sensitizer, we chose Ir(ppy) 3, which has a suitable T 1 energy level (T 1 = 2.48 eV) 42 for efficient triplet energy transfer to TP crystals (T 1 = 2.15 eV). 43 Dexter energy transfer requires close contact between Ir(ppy) 3 and TP molecules. Since TP is soluble in common organic solvents, the monolithic structure of TP-COMs is easily lost by organic solvents.…”