“…0.3 eV is found by our simulations, probably due to a non-perfect description of the solvent relaxation. 40 Because of the consistent uorescence intensityand the difficulties in measuring phosphorescencein biological and nanomaterials applications of Ce6 and porphyrin derivatives, [69][70][71] it seems unlikely that the emission is due to phosphorescence, and should rather be assigned to the emission from the singlet manifold. This aspect can be ascribed to two factors, rst a non-unitary population of the triplet manifold should be taken into account, leading to a signicant residual population of the singlet manifold, that can relax and lead to emission.…”
Linear and non-linear optical properties of a known photosensitizer producing singlet oxygen, chlorin e6, have been studied, including dynamics effects.
“…0.3 eV is found by our simulations, probably due to a non-perfect description of the solvent relaxation. 40 Because of the consistent uorescence intensityand the difficulties in measuring phosphorescencein biological and nanomaterials applications of Ce6 and porphyrin derivatives, [69][70][71] it seems unlikely that the emission is due to phosphorescence, and should rather be assigned to the emission from the singlet manifold. This aspect can be ascribed to two factors, rst a non-unitary population of the triplet manifold should be taken into account, leading to a signicant residual population of the singlet manifold, that can relax and lead to emission.…”
Linear and non-linear optical properties of a known photosensitizer producing singlet oxygen, chlorin e6, have been studied, including dynamics effects.
“…S 2À also causes a series of health problems owing to it having close association with living organisms in a variety of way. 2,3 Doing research about the detection of S 2À has become an important part of environment, human health and food safety for sustainable development. 4 Relevant medical research shows that free S 2À in biological systems is easily transformed into harmful hydrogen sulde at physiological pH value.…”
In this paper, 5,10,15,20-(4-sulphonatophenyl) porphyrin (TSPP) was synthesized by a facile route and used as a fluorescent probe to construct a sensor system based on the high water solubility and high quantum yield.
“…42 This PS has also been investigated for other biomedical applications including sensing, detection and imaging. [43][44][45][46] The prepared structures were characterized by using absorbance and fluorescence spectroscopy, transmission electron microscopy (TEM), dynamic light scattering (DLS) and zeta potential analysis. The dark toxicity and PDT effects were compared with Au NRs without PAA coating and free TMPyP in 2D monolayer cancer models and 3D compressed collagen constructs of A431 human squamous carcinoma.…”
In this paper, we show enhanced photodynamic therapy and fluorescence imaging using cationic porphyrin photosensitizer TMPyP loaded gold nanorods in 2D monolayer cultures and a novel in vitro head and neck squamous cell carcinoma 3D model.
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