A novel second-order non-linear optical coordination polymer with three-fold interpenetrated CdSO4-type network constructed by carboxylate–sulfonate ligands and strontium ions

Guan, Lei; Wang, Ying

doi:10.1016/j.jssc.2015.07.008

Cited by 11 publications

(1 citation statement)

References 45 publications

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“…In recent years, several coordination polymers with the SIP ligand have been described in the literature, for which the minor structural motif is a one-dimensional network (Arıcı et al, 2014;Franco et al, 2018). The great majority of these compounds are two-dimensional (Liu et al, 2008;Ding et al, 2014;Li et al, 2014;Chen et al 2015;Hou et al, 2016;Guan & Wang, 2016;Cheng et al, 2017;Singh et al, 2017) or threedimensional (Arıcı et al, 2014;Ding et al, 2014;Li et al, 2014;Voda et al, 2014;Liu et al, 2008;Guan & Wang, 2015;Zhu et al, 2016;Zhang et al, 2018). Comparing these compounds, it is possible to note that several types of topologies are observed for their nets.…”

Section: Resultsmentioning

confidence: 99%

Synthesis, crystal structure and topological analysis of a three-dimensional polymeric network based on zinc(II), potassium and 5-sulfobenzene-1,3-dicarboxylate (SIP)

et al. 2018

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Aromatic polycarboxylate linkers provide structural rigidity and strong interactions among the metal centre and the carboxylate O atoms. A new three-dimensional coordination polymer namely, catena-poly[potassium [tetraaqua(μ-5-sulfobenzene-1,3-dicarboxylato)zinc(II)]], {K[Zn(CHOS)(HO)]} or {K[Zn(SIP)(HO)]}, where SIP is 5-sulfobenzene-1,3-dicarboxylate or 5-sulfoisophthalate, was obtained and characterized by elemental analysis and IR vibrational spectroscopy, and the single-crystal structure was determined by X-ray diffraction analysis. The compound crystallizes in the monoclinic space group P2/n with Z = 4. Topological analysis revealed that K-O interactions form a two-dimensional network, which is uninodal 4-connected and can be described with a point symbol (4.6), and this plane network is classified as sql/Shubnikov. The layers are connected by Zn ions coordinated to the SIP linker, forming a three-dimensional network. This net is a trinodal (3,5,6)-connected system with point symbol (3.4.5.6.7.8).(3.4.5.6.7).(3.7).

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Section: Resultsmentioning

confidence: 99%

Synthesis, crystal structure and topological analysis of a three-dimensional polymeric network based on zinc(II), potassium and 5-sulfobenzene-1,3-dicarboxylate (SIP)

et al. 2018

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Syntheses, structure and properties of Alkaline-earth metal salts of 4-Nitrophenylacetic acid

2016

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The synthesis, crystal structure, spectral characteristics and thermal properties of alkaline-earth metal salts of 4-nitrophenylacetic acid (4-npaH) namely, [Mg(H 2 O) 6 ](4-npa) 2 •4H 2 O (4-npa = 4-nitrophenylacetate) (1), [Ca(H 2 O) 2 (4-npa) 2 ] (2) and [Sr(H 2 O) 3 (4-npa) 2 ]•4.5H 2 O(3) are reported. In 1, the 4-npa ion functions as a charge balancing counter anion for the octahedral [Mg(H 2 O) 6 ] 2+ unit with the Mg(II) ion situated on a centre of inversion. The two unique lattice water molecules link the [Mg(H 2 O) 6 ] 2+ cations and 4-npa anions with the aid of O-H• • • O interactions. Compounds 2 and 3 are one-dimensional (1-D) coordination polymers containing an eight coordinated Ca(II) situated in a general position and a nine coordinated Sr(II) located on a twofold axis. The μ 2-bridging tridentate binding modes of the crystallographically independent 4-npa ligands in 2 and the unique 4-npa ligand in 3 link the bivalent metal ions into an infinite chain with alternating Ca• • • Ca separations of 3.989 and 4.009 Å, respectively, and a single Sr• • • Sr separation of 4.194 Å in the 1-D chain.

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Control of topology in luminescent nitrobenzene-detecting cadmium camphorate polymers via hydrogen-bonding capable dipyridyl ligands

Przybyla

LaDuca

2018

Inorganica Chimica Acta

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A novel second-order non-linear optical coordination polymer with three-fold interpenetrated CdSO4-type network constructed by carboxylate–sulfonate ligands and strontium ions

Cited by 11 publications

References 45 publications

Synthesis, crystal structure and topological analysis of a three-dimensional polymeric network based on zinc(II), potassium and 5-sulfobenzene-1,3-dicarboxylate (SIP)

Synthesis, crystal structure and topological analysis of a three-dimensional polymeric network based on zinc(II), potassium and 5-sulfobenzene-1,3-dicarboxylate (SIP)

Syntheses, structure and properties of Alkaline-earth metal salts of 4-Nitrophenylacetic acid

Control of topology in luminescent nitrobenzene-detecting cadmium camphorate polymers via hydrogen-bonding capable dipyridyl ligands

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