A Novel Poly(vinyl chloride) Matrix Membrane Sensor for Batch and Flow-Injection Determinations of Thiocyanate, Cyanide and Some Metal Ions

Hassan, Saad S. M.; Badr, Ibrahim H. A.; Kamel, Ayman H.; Mohamed, Manal Sabry

doi:10.2116/analsci.25.911

Cited by 31 publications

(19 citation statements)

References 43 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…Most published methods for determination of cyanide exposure perform the analysis on blood samples. For humans, determination of cyanide exposure has been attempted from blood (34,37,45,49,51,55,59,82,95,, urine (49-53, 64, 142), saliva (54,55,64,70), expired air (56)(57)(58)(59)(60), and tissue (post-mortem) (51,129,140,143,144) samples. Blood may be the most versatile biological sample used to determine exposure to cyanide, because the analyses of cyanide, thiocyanate, ATCA, and cyanide-protein adducts can each be performed on blood samples.…”

Section: Biological Matrix Considerations For Verification Of Cyanidementioning

confidence: 99%

The Analysis of Cyanide and its Breakdown Products in Biological Samples

Logue¹,

Hinkens²,

Baskin³

et al. 2010

Critical Reviews in Analytical Chemistry

View full text Add to dashboard Cite

Cyanide is a toxic chemical that may be introduced into living organisms as a result of natural processes and/or anthropogenic uses (legal or illicit). Exposure to cyanide can be verified by analysis of cyanide or one of its breakdown products from biological samples. This verification may be important for medical, law-enforcement, military, forensic, research, or veterinary purposes. This review will discuss current bioanalytical techniques used for the verification of cyanide exposure, identify common problems associated with the analysis of cyanide and its biological breakdown products, and briefly address the metabolism and toxicokinetics of cyanide and its breakdown products in biological systems.

show abstract

Section: Biological Matrix Considerations For Verification Of Cyanidementioning

confidence: 99%

The Analysis of Cyanide and its Breakdown Products in Biological Samples

Logue¹,

Hinkens²,

Baskin³

et al. 2010

Critical Reviews in Analytical Chemistry

View full text Add to dashboard Cite

show abstract

“…The levels of UA in males are commonly higher than those of females. In recent works, the analyses of inorganic anions and/or UA in human saliva had been obtained by capillary ion electrophoresis (CIE) [5,7,8,15,16], microchip electrophoresis [17,18], ion chromatography (IC) [4,9,19,20], ion selective electrodes (ISE) [21], flow injection analysis (FIA) [22]. In particular, CIE has the advantages of rapid and simultaneous analyte detection as compared to ISE or FIA, and requires far smaller sample volumes as compared to IC.…”

Section: Introductionmentioning

confidence: 99%

Capillary ion electrophoresis of inorganic anions and uric acid in human saliva using a polyvinyl alcohol coated capillary column and hexamethonium chloride as additive of background electrolyte

Mori

Yamamoto

Kaseda

et al. 2012

Journal of Chromatography B

View full text Add to dashboard Cite

“…ISEs are one of the most important analytical methods due to their ability for enhancement of the detection efficiency with different ionophores, which have specific characteristics and features capable of simple, selective, and sensitive determination of different analytes in aqueous and biological solutions [11][12][13]. Among these ionophores, there are molecular imprinted polymers (MIPs), which can be manufactured with specific characters that compatible with their detection of the analyte in the different solutions.…”

Section: Introductionmentioning

confidence: 99%

Modified Potentiometric Screen-Printed Electrodes Based on Imprinting Character for Sodium Deoxycholate Determination

et al. 2020

View full text Add to dashboard Cite

Potentiometric sensors have a great influence on the determination of most various compounds in their matrices. Therefore, efficient and new sensors were introduced to measure sodium Deoxycholate (NaDC) as a bile acid salt. These sensors are based on NaDC imprinted polymer (MIP) as sensory element. The MIP beads were synthesized using thermal polymerization pathway, in which acrylamide (AAm), ethylene glycol dimethacrylate (EGDMA), NaDC, and benzoyl peroxide (BPO) were used as the functional monomer, cross-linker, template, and initiator, respectively. The proposed sensors were fabricated using a coated screen-printed platform and the sensing membrane was modified by single-walled carbon nanotubes (SWCNTs) as an ion-to-electron transducer. The sensors exhibited high sensitivity that reached 4.7 × 10−5 M of near-Nernestian slope (−60.1 ± 0.9 mV/decade, r2 = 0.999 (n= 5)). In addition, the sensors revealed high selectivity, long lifetime, high potential stability, and conductivity that ensure reproducible and accurate results over a long time. MIP characterization was performed using Fourier Transform-Infrared (FT-IR) and a scanning electron microscope (SEM). Regarding the interaction of NaDC with serum albumin (SA), albumin is determined in human serum samples as human serum albumin (HSA), which was collected from different volunteers of different ages and gender.

show abstract

A Novel Poly(vinyl chloride) Matrix Membrane Sensor for Batch and Flow-Injection Determinations of Thiocyanate, Cyanide and Some Metal Ions

Cited by 31 publications

References 43 publications

The Analysis of Cyanide and its Breakdown Products in Biological Samples

The Analysis of Cyanide and its Breakdown Products in Biological Samples

Capillary ion electrophoresis of inorganic anions and uric acid in human saliva using a polyvinyl alcohol coated capillary column and hexamethonium chloride as additive of background electrolyte

Modified Potentiometric Screen-Printed Electrodes Based on Imprinting Character for Sodium Deoxycholate Determination

Contact Info

Product

Resources

About