1997
DOI: 10.1107/s0108270197009700
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A New Zinc Pyrovanadate, Zn3(OH)2V2O7.2H2O, from X-ray Powder Data

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Cited by 55 publications
(21 citation statements)
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“…Thus, we attempted to substitute Cu 2 ions by nonmagnetic Zn 2 ions. Zn 3 V 2 O 7 OH 2 2H 2 O, with the same stoichiometry [11], has a crystal structure slightly different from that of CVO. Both the lattice parameter and atom positions are, however, quite similar between the Cu and Zn systems.…”
mentioning
confidence: 94%
“…Thus, we attempted to substitute Cu 2 ions by nonmagnetic Zn 2 ions. Zn 3 V 2 O 7 OH 2 2H 2 O, with the same stoichiometry [11], has a crystal structure slightly different from that of CVO. Both the lattice parameter and atom positions are, however, quite similar between the Cu and Zn systems.…”
mentioning
confidence: 94%
“…Volborthite adopts monoclinic symmetry due to the significant Jahn-Teller distortion of one of the two symmetrically non-equivalent CuO 6 octahedra. Engelhauptite Raman data -this work *The unit-cell parameters of the synthetic analogue of martyite are: a = 6.05098(5) Å, c = 7.19498 Å, V = 228.15 Å 3 ; Zavalii et al (1997) …”
Section: Discussionmentioning
confidence: 99%
“…As a mineral known since the 18th century, Cu 3 (OH) 2 V 2 O 7 ·nH 2 O can now be prepared in laboratory via an aqueous solution method [11][12][13]. It has a novel structure that consist of alternated Cu-O layer and V-O layer with channels in V-O layer, which is similar with that of Zn 3 (OH) 2 V 2 O 7 ·nH 2 O [14][15][16][17][18][19]. Such a channel structure will facilitate the insertion and extraction, making Cu 3 (OH) 2 [20].…”
Section: Introductionmentioning
confidence: 99%