A New Sorbent for Selective Separation of Metal: Polyethylenimine Methylenephosphonic Acid

Abderrahim, Omar; Didi, Mohamed Amine; Moreau, Bernard; Villemin, Didier

doi:10.1080/07366290600952519

Cited by 28 publications

(17 citation statements)

References 22 publications

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“…A number of sorbents, such as amberlite XAD [13], amberlite XAD-2-functionalized with 2-(2 I -benzothiazolylazo)-p-cresol (BTAC-XAD) [18], organically modified clay [19], modified silica gel [20][21][22][23], polyethylenimine methylenephosphonic acid (PEIMPA) [24], and calixarenes [25,26], have been used as solid-phase extraction materials. Among these, silica gel, especially when modified with different metal-chelating organic compounds and microorganisms [27][28][29][30][31], has received great attention due to a number of advantages, such as good mechanical and thermal stability, selectivity, no swelling, and easy regeneration [32].…”

Section: Introductionmentioning

confidence: 99%

Determination of Copper in Water Samples after Solid‐phase Extraction Using Dimethylglyoxime‐modified Silica

Anılan

Gedikbey

Akar³

2010

CLEAN Soil Air Water

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This work describes the modification of silica gel with dimethylglyoxime, in order to prepare an effective sorbent for the preconcentration and determination of copper. The sorption capacity of dimethylglyoxime-modified silica-gel (DMGMS) was 71.37 mg g -1 and the optimum pH for the quantitative recovery of copper was found to be 5.0. The optimum flow rate, sorbent amount, and sample volume were 1 mL min -1 , 300 mg, and 50 mL, respectively. 10 mL of 0.1 mol L -1 HCl was the most suitable eluent. The detection limit of copper was 6.0 ng mL -1 . The recommended method, for the determination of copper, is simple and reliable, without any notable matrix effect and can be successfully applied to environmental water samples. Copper recovery in the range from 99 -100% was obtained from seawater and thermal spring water using this method. The method was applied to standard reference materials, NIST-1515 (apple leaves) and NIST-1643e (simulated fresh water), for the determination of copper and the results were in good agreement with certified values.

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Section: Introductionmentioning

confidence: 99%

Determination of Copper in Water Samples after Solid‐phase Extraction Using Dimethylglyoxime‐modified Silica

Anılan

Gedikbey

Akar³

2010

CLEAN Soil Air Water

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“…11 shows the extraction yield as a function of initial pH, where the extraction efficiency increases rapidly with increasing initial pH. It reaches a maximum value around pH 7.0 for fine particles and pH 6.0 for the large particles; this is due to the favorable conditions for the complex formation of neodymium with particles magnetic in this pH [33].The progressive decrease in the retention of neodymium ions at low pH is due to the competition of hydrogen with neodymium for sorption sites on particles magnetic and to the protonation of the active groups [21,22,33]. The dépro-tonation during the increase of pH returns the favorable approach of the cations [34].…”

Section: Effect Of Initial Phmentioning

confidence: 90%

“…Reactions were performed both by heating and under microwave irradiation [19,20]. In a second time, scope of application was extended to phosphonation of amine based polymers like PEI in aqueous solution, affording phosphonated PEI [21][22][23][24][25].…”

Section: Preparation Of Polymermentioning

confidence: 99%

Neodymium(III) removal by functionalized magnetic nanoparticles

Miraoui

Didi

Villemin

2015

J Radioanal Nucl Chem

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In this paper, neodymium removed by liquidsolid extraction is made by magnetic nanoparticles functionalized by the poly(aminoethylene N-methyl 1-formic acid, 1-phosphonic acid) (PAEMFP), with two different sizes. For a quantity of 0.01 g of magnetic particles some parameters were studied. Optimal extraction yield was achieved in a initial pH equal at 7.0 for fine particles and pH 6.0 for the large particles. The experimental capacity obtained was 25 mg g -1 for larges particles and 23 mg g -1 for fines particles. The quantitative elution study of neodymium(III) can be realized with acetic acid 0.5 mol L -1 after 120 min of shaking for two sizes.

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“…They are very similar and contain different overlapping bands characteristic of the resin structure. A broad band in the 3600−3200 cm −1 region is characteristic of the O-H groups of the acid and residual hydration water (Abderrahim et al 2006;Lazar et al 2014). The peaks at about 2926 cm −1 are due to the aliphatic C-H stretching vibrations derived from the methyl groups in the main chain of resin.…”

Section: Ftir Studiesmentioning

confidence: 99%

Recovery of metals from waste nickel-metal hydride batteries using multifunctional Diphonix resin

2019

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In this study, Diphonix resin containing sulfonic, diphosphonic and carboxylic groups was used to evaluate the adsorption capacity of metal ions contained in the nickel-metal hydride batteries (Ni-MH). This type of ion exchanger can be considered as the multifunctional material having great affinity to many metal ions. Using Diphonix resin adsorption process was carried out for La(III) and Ni(II) ions to characterize kinetic, adsorption and thermodynamic parameters. Preliminary studies of the Nd(III), Ce(III), La(III), Fe(III), Co(II), Ni(II), Cu(II) and Zn(II) metal ions mixture were also performed. The best results of adsorption studies were obtained using 0.2 M HNO 3. Diphonix resin exhibits especially good adsorptive properties with respect to rare earth element ions (adsorption efficiency of about 100%) in comparison with the heavy metal ions in the second oxidation state (about 50% or below). The series of affinity of the resin for the studied ions can be presented as follows: La(III) > Fe(III) > Nd(III) > Ce(III) > Cu(II) > Zn(II) > Co(II) > Ni(II). The obtained results confirmed the possibility of further use of the resin for the recovery and separation of rare earth elements from solutions after Ni-MH batteries leaching.

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A New Sorbent for Selective Separation of Metal: Polyethylenimine Methylenephosphonic Acid

Cited by 28 publications

References 22 publications

Determination of Copper in Water Samples after Solid‐phase Extraction Using Dimethylglyoxime‐modified Silica

Determination of Copper in Water Samples after Solid‐phase Extraction Using Dimethylglyoxime‐modified Silica

Neodymium(III) removal by functionalized magnetic nanoparticles

Recovery of metals from waste nickel-metal hydride batteries using multifunctional Diphonix resin

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