A new iron-based metal–organic framework with enhancing catalysis activity for benzene hydroxylation

Abstract

A new Fe-based MOFs catalyst was used for benzene hydroxylation with the high phenol yield (64.5%) and selectivity (92.9%).

An efficient photocatalysis-self-Fenton system based on Fe(ii)-MOF/g-C3N4for direct hydroxylation of benzene to phenol

“…8 Tu has synthesized a novel Fe-based MOF with a topological framework as a recyclable heterogeneous catalyst for benzene hydroxylation. 9 The Yang group reported a mixed valent Fe-based MOF, which greatly enhanced Fenton performance and further improved the efficiency of benzene hydroxylation to produce phenol. 10 To a certain extent, although MOF materials could be applied to the direct hydroxylation of benzene to prepare phenol, its limited response to light impeded its wide application.…”

Pore size effect of 1,3,6,8-tetrakis(4-carboxyphenyl)pyrene-based metal-organic frameworks for enhanced SF6 adsorption with high selectivity

“…The crystallographic micropore sizes of JXNU-5 and NU-1000 range between 5 and 9 Å [24,42] and may be suitable for SF 6 sorption. We previously demonstrated that pore sizes of ~7 Å could enhance the sorption of SF 6 (5.5 Å kinetic diameter [36]) on mixed-linker ZIF-7-8s [43].…”

Metal–Organic Frameworks Constructed from Iron‐Series Elements for Supercapacitors

“…[ 59–62 ] Due to their unique characteristics, they were usually used as catalysts in light and electric fields. [ 63–67 ] Except for that, acting as electrode materials for SCs, several groups utilized the Cr‐based MIL compositing with conductive units to prepare the electrodes in recent years. [ 68,69 ] As to Fe‐based MOFs, to date, they have only scarcely been investigated for SCs probably due to the more insufficient conductivity and lower degree of crystallinity.…”