Continuous monitoring of the central-blood-pressure waveform from deeply
embedded vessels, such as the carotid artery and jugular vein, has clinical
value for the prediction of all-cause cardiovascular mortality. However,
existing non-invasive approaches, including photoplethysmography and tonometry,
only enable access to the superficial peripheral vasculature. Although current
ultrasonic technologies allow non-invasive deep-tissue observation, unstable
coupling with the tissue surface resulting from the bulkiness and rigidity of
conventional ultrasound probes introduces usability constraints. Here, we
describe the design and operation of an ultrasonic device that is conformal to
the skin and capable of capturing blood-pressure waveforms at deeply embedded
arterial and venous sites. The wearable device is ultrathin (240 μm) and
stretchable (with strains up to 60%), and enables the non-invasive, continuous
and accurate monitoring of cardiovascular events from multiple body locations,
which should facilitate its use in a variety of clinical environments.
One two-dimensional Fe-based metal−organic framework (FeSC1) and one one-dimensional coordination polymer (FeSC2) have been solvothermally prepared through the reaction among FeSO 4 •7H 2 O, the tripodal ligand 4,4′,4″-striazine-2,4,6-triyl-tribenzoate (H 3 TATB), and flexible secondary building blocks p/m-bis((1H-imidazole-1-yl)methyl)benzene (bib). Given that their abundant interlayer spaces and different coordination modes, two compounds have been employed as battery-type electrodes to understand how void space and different coordination modes affect their performances in three-electrode electrochemical systems. Both materials exhibit outstanding but different electrochemical performances (including distinct capacities and charge-transfer abilities) under three-electrode configurations, where the charge storage for each electrode material is mainly dominated by the diffusion-controlled section (i ∝ v 0.5 ) through power-law equations. Additionally, the partial phase transformations to more stable FeOOH are also detected in the longterm cycling loops. After coupling with the capacitive carbon-based electrode to assemble into the semi-solid-state battery− supercapacitor-hybrid (sss-BSH) devices, the sss-FeSC1//AC BSH device delivers excellent capacitance, superior energy and power density, and longstanding endurance as well as the potential practical property.
As a new generation of two-dimensional (2D) materials, 2D metal-organic frameworks (MOFs) can provide uniform active sites and unique open channels as well as excellent catalytic activities, interesting magnetic properties,...
Iron‐series (Fe, Co, and Ni) containing metal–organic frameworks (MOFs) have gained great concern in supercapacitors (SCs) because of their tailorable architectures, multiple redox‐active sites, and intriguing properties. Given the importance of porosities in MOFs for charge transmission, an essential assessment of their designs, preparation methods, and engineering technologies is strongly required to further explore and optimize SCs. Through empowering conductive backbones and redox‐active centers, iron‐series containing MOF‐based electrodes have made outstanding achievements recently. This review aims to summarize these core reports on iron‐series containing MOFs. Correspondingly, the design strategy, the reason for compositing, the strategy of introducing heteroatoms, and the current divergences on structural alteration mechanisms are discussed. Potential bottleneck issues and coping strategies are also perspectively discussed to guide future optimization.
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