A new [As3Mo3O15]3− fragment decorated with Cu(I)-imi (imi=imidazole) complexes: Synthesis, structure and electrochemical properties

A novel polyoxometalate cluster decorated with the directly coordinated organonitrogen ligands: [As(phen)]2[As2Mo2O14]

“…In fact, our group has been focused on the modification of molybdenum arsenate [22], and accordingly we attempt to carry out obtaining new organic-inorganic hybrid molybdenum arsenate compounds with novel structures and interested properties by exploring the rational reaction condition, and then further investigate their potential applications in material science.…”

Arsenomolybdates for Photocatalytic Degradation of Organic Dyes

“…[33]. {As 2 Mo 9 }) type, is derived from the trivacant Keggin moiety, which is capped by a triangular pyramidal {AsO 3 } group, e.g., [41], and so on. The novel arsenomolybdate structure is gaining more and more attention.…”

“…Experimental and theoretical studies of arsenomolybdates photocatalysis have revealed that it typically proceeds based on the following mechanism [41,42,48,52]: Irradiated of arsenomolybdates by UV light with energy equal to or greater than the E g value of itself, which induces intramolecular charge-transfer from the HOMO of O to the LUMO of Mo, leading to the formation of photoexcited states, subsequently photogenerated electron-hole pairs were generated. The O 2 captures electron to form • O 2ˉa nd the hole reacts with H 2 OorOH À ions to form • OH.…”

An electrochemical sensing platform based on a new copper complex for the determination of hydrogen peroxide and nitrite

“…Wang et al studied the electrocatalytic reduction of NO − 2 by copper complexes containing the chelating ligand dipyrido[3,2-d:2 ,3 -f]quinoxaline [18,19]. The electrochemistry and electrocatalysis of copper complexes with various ligands have been investigated by several groups [20][21][22].…”