2006
DOI: 10.1088/0957-4484/17/9/036
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A nanocapacitor with giant dielectric permittivity

Abstract: A nanocapacitor with ultra high capacitance (718 ± 0.2 pF) has been fabricated using electro-deposited Au nanowires manipulated between two Au microelectrodes by the dielectrophoresis technique. A high dc resistance value (∼100 M ) and nonlinear current-voltage characteristics indicate the formation of a dielectric interface between the nanowires. From frequency dependent conductivity, it is seen that the interface exhibits a giant dielectric permittivity (ε ∼ 1.8 × 10 7 ), which shows no frequency dispersion … Show more

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Cited by 12 publications
(8 citation statements)
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References 17 publications
(27 reference statements)
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“…The geometric depolarization factor vanishes for q1D symmetry, leading to giant dielectric constants ɛ which rise as the filament length increases56. This effect was recently observed in Au nanowires57, with ɛ reaching 10 7 . In Na 2− δ Mo 6 Se 6 , we therefore anticipate that the long-range Coulomb repulsion in an individual (Mo 6 Se 6 ) l filament ( l <∞) will be efficiently screened by neighbouring filaments29.…”
Section: Discussionmentioning
confidence: 63%
“…The geometric depolarization factor vanishes for q1D symmetry, leading to giant dielectric constants ɛ which rise as the filament length increases56. This effect was recently observed in Au nanowires57, with ɛ reaching 10 7 . In Na 2− δ Mo 6 Se 6 , we therefore anticipate that the long-range Coulomb repulsion in an individual (Mo 6 Se 6 ) l filament ( l <∞) will be efficiently screened by neighbouring filaments29.…”
Section: Discussionmentioning
confidence: 63%
“…88 and 89 for more details) present experimental data on capacitors with nanodielectrics which are reportedly characterized by gigantic k ∼ 10 7 -10 10 and a large potential in energy storage. [89][90][91] The analysis of the data does not support the expectations. In a plane capacitor, the surface charge density δ Q on atomically smooth electrodes is limited by δ Qmax ∼ 1.5 × 10 −4 C/cm 2 (an ion charge of one sign on crystallographic planes with small indices, the concentration n ≈ 10 15 cm −2 ).…”
Section: 23mentioning
confidence: 99%
“…Energy storage devices such as supercapacitors and batteries have always drawn much attention for their potential applications [ 23 ]. Conventional batteries can store substantial amounts of energy but they have the drawback of their charging time that is much longer than that of a capacitor.…”
Section: Introductionmentioning
confidence: 99%