A molecular Pd(ii) complex incorporated into a MOF as a highly active single-site heterogeneous catalyst for C–Cl bond activation

Engineering Metal–Organic Framework Catalysts for C−C and C−X Coupling Reactions: Advances in Reticular Approaches from 2014–2018

“…Pd II -decorated UiO-67 was used by Chen and co-workers [159] for Heck coupling. [(5,5'-Dicarboxy-2,2'-bipyridine)palladium(II)] dichloride was synthesized from (2,2'-bipyridine)-5,5'-dicarboxylic acid dimethyl ester and PdCl 2 (CH 3 CN) 2 .S ubsequentt reatment of ZrCl 4 with biphenyl dicarboxylic acid and the Pd II complex yieldedt he requisite MOF.T he catalyst was characterized by using PXRD,X PS, ICP-OES, TEM, and BET.T he surfacea rea of the catalyst was experimentally determined to be 2000 m 2 g À1 .T he absence of Pd congregationw as confirmed by using TEM images.…”

Heterogeneous heck coupling in multivariate metal–organic frameworks for enhanced selectivity

“…Due to its outstanding stereoselectivity, Heck coupling is of particular interest in the pharmaceutical chemistry [18] and has been demonstrated in both homogeneous and heterogeneous systems previously, including other MOFs [19][20][21][22][23]. To highlight the advantage of combining the MTV approach with postmodification, we investigated the Heck coupling reaction for the synthesis of resveratrol trimethyl ether, a pharmaceutically relevant precursor.…”

Incorporation of PdCl2P2 Complexes in Ni‐MOF for Catalyzing Heck Arylation of Functionalized Olefins

“…However, the incorporation of the phosphine complexes into a MOF material has never been examined yet. The previously reported Pd‐phosphine‐MOF composites were formed by the direct coordination of Pd to the ligand used as a linker …”