A metal–organic framework containing meso-helical chains: Synthesis, characterization and luminescent property

Two novel coordination polymers based on mixed ligands, [Zn(dpb)(bdc)(H2O)]n (1) and [Cd(dpb)(bbdc)(H2O)(DMF)]n (2) [dpb = 1, 4‐bis(pyridin‐3‐ylmethoxy)benzene, H2bdc = 1, 4‐benzenedicarboxylate, H2bbdc = 4, 4′‐dibenzenedicarboxylate], were synthesized under hydrothermal conditions. Compound 1 forms meso‐helical chain and shows three fold interpenetrating architecture with 4‐connected net {6 6} diamond topology. Compound 2 is a left‐ and right‐handed helical layer, which are interacted by π–π stacking interactions to construct a 3D framework. The luminescent properties of the compounds are discussed.

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Modulated assembly of interdigitated 1D isolated tube and 2D highly undulating layer based on N-donor ligand and multidentate carboxylic acid

Zhang

Chen

Song

et al. 2012

Inorganic Chemistry Communications

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A metal–organic framework containing meso-helical chains: Synthesis, characterization and luminescent property

Cited by 15 publications

References 38 publications

Homochiral, Supramolecular Frameworks Built from a Zinc(II) Tetramer or Cadmium(II) Dimer Containing Enantiopure Carboxylate Ligands Functionalized with a Strong π···π Stacking Synthon

Homochiral, Supramolecular Frameworks Built from a Zinc(II) Tetramer or Cadmium(II) Dimer Containing Enantiopure Carboxylate Ligands Functionalized with a Strong π···π Stacking Synthon

Synthesis, Structures, and Properties of two Helical Structures from Rigid Carboxylate Ligand and Flexible N‐Bridging Ligands

Modulated assembly of interdigitated 1D isolated tube and 2D highly undulating layer based on N-donor ligand and multidentate carboxylic acid

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