1977
DOI: 10.1002/pssb.2220840203
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A low temperature equation of state for monovalent metals

Abstract: An equation of state for metals based upon a simple model, which ignores the effect of free electrons, was given in an earlier paper. An improved equation of state is obtained for monovalent metals by taking account of the electronic contribution in the free energy expression. This result is used to explain the thermal expansivity of copper in the range between 1 and 12 K. The same set of parameters give theoretical specific heat values which are in fairly good agreement with the reported experimental data in … Show more

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Cited by 3 publications
(1 citation statement)
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“…For actual calculations in the high temperature region (above the Debye temperature), it is convenient to make use of the Einstein approximation according to which vf = v for all i. I n fact the results obtained by the use of the Debye spectruni in this temperature region almost coincide with the simpler Einstein version. However, in the low temperature region the Einstein approximation fails and one has to make use of the Debye spectrum to get agreement with experiment [3].…”
Section: Comparison With Experimentsmentioning
confidence: 99%
“…For actual calculations in the high temperature region (above the Debye temperature), it is convenient to make use of the Einstein approximation according to which vf = v for all i. I n fact the results obtained by the use of the Debye spectruni in this temperature region almost coincide with the simpler Einstein version. However, in the low temperature region the Einstein approximation fails and one has to make use of the Debye spectrum to get agreement with experiment [3].…”
Section: Comparison With Experimentsmentioning
confidence: 99%