A kinetic study on the dissolution of disperse dyes in the presence of intensifying additives

Veleva, S.; Georgieva, A.; Pishev, D. I.

doi:10.1111/j.1478-4408.2000.tb00037.x

Cited by 1 publication

(2 citation statements)

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“…Kinetic parameters for dye solubility are reported in Table . The calculations were performed using Eqns and . κ and κ′ are proportional to dye solubility and the rate constant of the process; ln (κ′/κ) is a constant value.…”

Section: Resultsmentioning

confidence: 99%

“…where t and C s are time and saturation concentration, respectively, S 0 and S s are the initial surface area of the solute and the surface area of the solute at the saturation concentration, respectively, S 0 / S s shows the reduction of accessible dye surface during dissolution , and C final is the maximum measured concentration of dye at the finishing point .…”

Section: Resultsmentioning

confidence: 99%

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Effects of the side chain density of polycarboxylate dispersants on dye dispersion properties

Gharanjig

Khosravi

2019

Coloration Technology

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Comb‐like polycarboxylates were synthesised by copolymerisation of methacrylic acid and nonylphenol polyethylene glycol methacrylate ester, and can be used as dye dispersants. In order to achieve good dispersive ability, three polycarboxylates were synthesised, each having a different side chain density. The side chain density of polymers was controlled by different ratios of monomers in the copolymerisation process. Acidic polymers were neutralised using sodium hydroxide. These polymers exhibit good dispersing performance, such that carboxylate groups are adsorbed onto the dye particle surface and the side chains enable the formation of a thick layer, thus providing the steric hindrance effect. Improvement of dye dissolution in the presence of polycarboxylates was studied. Polymers with a lower side chain density demonstrated a higher dye dissolution in water, which could be as a result of more effective adsorption of dispersant on the dye surface (CI Disperse Blue 79). The dyeing performance of the prepared dye dispersions on polyester was investigated. Spectrophotometric analysis of dyed fabrics using synthesised polycarboxylates demonstrates that there should be an optimum side chain density of polymer in order to control both dye solubility and dispersive ability. The result of turbidimetry and particle size analysis have proven this phenomenon. A comb‐like polycarboxylate with optimum side chain density was a better dye dispersant compared with a commercial sodium naphthalene sulphonate compound, as a result of its better heat stability.

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Section: Resultsmentioning

confidence: 99%

Section: Resultsmentioning

confidence: 99%