Alumina (Al 2 O 3 ) thin films have been deposited on silicon substrates by atomic layer deposition at 200ºC using TMA as Al precursor and H 2 O or O 3 as oxygen precursor. The growth rate has been found to be lower for ozone-based processes as compared to H 2 O. The electrical characterization of the deposited layers has shown that when using O 3 the films exhibit larger defect densities as compared to those grown using H 2 O, although these show larger trapping. A post deposition anneal process at 650ºC has been shown to lower the defect densities, being this annealing more efficient for O 3 -grown layers. The effect of post-metallization annealing in forming gas is also investigated.