“…11 After the programming operation, the device with an annealing temperature of 950 C performed better, with a larger positive V FB (flat band voltage) shift than the device with the lower annealing temperature of 800 C. 12,13 Therefore, proper annealing can also enhance the P/E speed, because annealing improves the high-k layer quality and increases electron trapping by increasing the effective electric field across the tunneling oxide. 14 Material analyses, including XRD and AFM, were conducted in order to gain an in-depth understanding of the improvements in the electrical characteristics of the device. In order to probe into the crystalline structure of the high-k HfTiO 4 , XRD was used to analyze the as-deposited sample and the samples with RTA treatment at 600 C, 700 C, 800 C, 900 C, and 950 C, respectively.…”